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Selective Alkylation of (Hetero)Aromatic Amines with Alcohols Catalyzed by a Ruthenium Pincer Complex
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- Agrawal, Santosh (author)
- Stockholms universitet,Institutionen för organisk kemi
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- Lenormand, Maud (author)
- Stockholms universitet,Institutionen för organisk kemi
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- Martín-Matute, Belén (author)
- Stockholms universitet,Institutionen för organisk kemi
- (creator_code:org_t)
- 2012-02-27
- 2012
- English.
- In: Organic Letters. - : American Chemical Society (ACS). - 1523-7060 .- 1523-7052. ; 14:6, s. 1456-1459
- Journal article (peer-reviewed)
Abstract
Subject headings
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- A readily available pincer ruthenium(II) complex catalyzes the selective monoalkylation of (hetero)aromatic amines with a wide range of primary alcohols (including pyridine-, furan-, and thiophene-substituted alcohols) with high efficiency when used in low catalyst loadings (1 mol %). Tertiary amine formation via polyalkylation does not occur, making this ruthenium system an excellent catalyst for the synthesis of sec-amines.
Subject headings
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
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- ref (subject category)
- art (subject category)
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