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CONTACT ION-PAIR FORMATION AND ETHER OXYGEN COORDINATION IN THE POLYMER ELECTROLYTES M[N(CF3SO2)(2)](2)PEO(N) FOR M=MG, CA, SR AND BA
- BAKKER, ALBERT (author)
- GEJJI, SHRIDHAR (author)
- LINDGREN, JAN (author)
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- PROBST, MICHAEL M (author)
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- (creator_code:org_t)
- 1995
- 1995
- English.
- In: Polymer. - 0032-3861 .- 1873-2291. ; 36:23, s. 4371-4378
- Journal article (peer-reviewed)
Abstract
Subject headings
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- The polymer electrolytes M[N(CF3SO2)(2)](2)PEO(n) for M = Mg, Ca, Sr and Ba have been investigated using infra-red spectroscopy, differential scanning calorimetry and impedance spectroscopy. The effects of varying concentration (n = 6-40) and temperature (25-95 degrees C) on the contact ion pair formation and cation coordination have been studied. Contact ion pairs are only found for the most concentrated samples (n < 9). Ion pairs occur with two types of structures: one type is found far samples containing Mg2+ and the other for samples with Ca2+, Sr2+ and Ba2+. The conductivities of the samples are discussed in terms of radii and coordination numbers of the cations.
Subject headings
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Keyword
- POLYMER ELECTROLYTES
- CONTACT ION PAIR FORMATION
- CATION COORDINATION
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- art (subject category)
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- Uppsala University
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