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Quantum-matter photonic framework perspective of chemical processes : Entanglement shifts in HCN/CNH isomerization
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- Tapia-Olivares, Orlando (author)
- Uppsala universitet,Fysikalisk kemi
- (creator_code:org_t)
- 2015-06-30
- 2015
- English.
- In: International Journal of Quantum Chemistry. - : Wiley. - 0020-7608 .- 1097-461X. ; 115:20, s. 1490-1500
- Journal article (peer-reviewed)
Abstract
Subject headings
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- A complete electro-nuclear (EN) basis set and quantum electrodynamics bases in photon number scheme combines to form photonic bases sets. The EN q-states can hence be modulated by appropriate external electromagnetic sources. Quantum determinants for HCN/CNH isomerization within photonic bases are elaborated that rationalize quantum state changes as if it were an apparent unimolecular process. Topologic label of base states permit linking with those obtained with semiclassic schemes. A comparison of results leads to conclude that both schemes can turn out to be complementary. The q-scheme yielding more detailed information that the semiclassic one as expected.
Subject headings
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
Keyword
- quantum physics
- photonic basis
- photonic chemistry
- entanglement
- topologic labeled bases
Publication and Content Type
- ref (subject category)
- art (subject category)
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