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Development of a mo...
Development of a molecularly imprinted polymer electrochemical sensor and its application for sensitive detection and determination of malathion in olive fruits and oils
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- Aghoutane, Youssra (author)
- Biotechnology Agroalimentary and Biomedical Analysis Group, Department of Biology, Faculty of Sciences, Moulay Ismaïl University, B.P. 11201, Zitoune, Meknes, Morocco; Sensor Electronic & Instrumentation Group, Department of Physics, Faculty of Sciences, Moulay Ismaïl University, B.P. 11201, Zitoune, Meknes, Morocco
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- Diouf, Alassane (author)
- Biotechnology Agroalimentary and Biomedical Analysis Group, Department of Biology, Faculty of Sciences, Moulay Ismaïl University, B.P. 11201, Zitoune, Meknes, Morocco; Sensor Electronic & Instrumentation Group, Department of Physics, Faculty of Sciences, Moulay Ismaïl University, B.P. 11201, Zitoune, Meknes, Morocco
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- Österlund, Lars, 1967- (author)
- Uppsala universitet,Fasta tillståndets fysik
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- Bouchikhi, Benachir (author)
- Sensor Electronic & Instrumentation Group, Department of Physics, Faculty of Sciences, Moulay Ismaïl University, B.P. 11201, Zitoune, Meknes, Morocco
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- El Bari, Nezha el bari (author)
- Biotechnology Agroalimentary and Biomedical Analysis Group, Department of Biology, Faculty of Sciences, Moulay Ismaïl University, B.P. 11201, Zitoune, Meknes, Morocco
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Biotechnology Agroalimentary and Biomedical Analysis Group, Department of Biology, Faculty of Sciences, Moulay Ismaïl University, BP. 11201, Zitoune, Meknes, Morocco; Sensor Electronic & Instrumentation Group, Department of Physics, Faculty of Sciences, Moulay Ismaïl University, B.P. 11201, Zitoune, Meknes, Morocco Fasta tillståndets fysik (creator_code:org_t)
- Elsevier, 2020
- 2020
- English.
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In: Bioelectrochemistry. - : Elsevier. - 1567-5394 .- 1878-562X. ; 132
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- Malathion (MAL) is an organophosphorus (OP) insecticide. It is a cholinesterase inhibitor, 15 which can pose serious health and environmental problems. In this study, a sensitive and 16 selective molecular imprinted polymer (MIP) based on screen-printed gold electrodes (Au-17 SPE) for MAL detection in olive oils and fruits, was devised. The MIP sensor was prepared 18 using acrylamide as the functional monomer and MAL as the template. Subsequently, the 19 morphology of the electrode surface was studied by scanning electron microscopy (SEM) and 20 atomic force microscopy (AFM). The electrochemical characterization of the developed MIP 21 sensor was performed by cyclic voltammetry (CV), differential pulse voltammetry (DPV), 22 and electrochemical impedance spectroscopy (EIS) techniques. The operational repeatability 23 and stability of the sensor were studied. It was found to have a dynamic concentration range 24 of (0.1 pg mL-1-1000 pg mL-1) and a low limit of detection (LOD) of 0.06 pg mL-1. 25 Furthermore, the sensor was employed to determine MAL content in olive oil with a recovery 26 rate of 87.9% and a relative standard deviation of 8%. It was successfully applied for MAL 27 determination in real samples and promise to open new opportunities for the detection of OP 28 pesticides residues in various food products, as well as in environmental applications.
Subject headings
- NATURVETENSKAP -- Kemi -- Analytisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Analytical Chemistry (hsv//eng)
Keyword
- Molecularly imprinted polymer; Screen printed gold electrode; Electrochemical 30 sensor; Malathion; Olive oils; olive fruits
- Kemi med inriktning mot analytisk kemi
- Chemistry with specialization in Analytical Chemistry
- Teknisk fysik med inriktning mot materialvetenskap
- Engineering Science with specialization in Materials Science
Publication and Content Type
- ref (subject category)
- art (subject category)
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