id:"swepub:oai:DiVA.org:uu-482745"
Search: id:"swepub:oai:DiVA.org:uu-482745" > Solvent Gaming Chem...
- 1 of 1
- Previous record
- Next record
- To hitlist
Solvent Gaming Chemistry to Control the Quality of Halide Perovskite Thin Films for Photovoltaics
-
- Huang, Xiaofeng (author)
- Xiamen Univ, Pen Tung Sah Inst Micronano Sci & Technol, Coll Chem & Chem Engn,State Key Lab Phys Chem Soli, Collaborat Innovat Ctr Chem Energy Mat,Natl & Loca, Xiamen 361005, Peoples R China.
-
- Deng, Guocheng (author)
- Xiamen Univ, Pen Tung Sah Inst Micronano Sci & Technol, Coll Chem & Chem Engn,State Key Lab Phys Chem Soli, Collaborat Innovat Ctr Chem Energy Mat,Natl & Loca, Xiamen 361005, Peoples R China.
-
- Zhan, Shaoqi (author)
- Uppsala universitet,Institutionen för kemi - BMC
- show more...
- show less...
- Xiamen Univ, Pen Tung Sah Inst Micronano Sci & Technol, Coll Chem & Chem Engn,State Key Lab Phys Chem Soli, Collaborat Innovat Ctr Chem Energy Mat,Natl & Loca, Xiamen 361005, Peoples R China Institutionen för kemi - BMC (creator_code:org_t)
- 2022-07-19
- 2022
- English.
- In: ACS CENTRAL SCIENCE. - : American Chemical Society (ACS). - 2374-7943 .- 2374-7951. ; 8:7, s. 1008-1016
- Journal article (peer-reviewed)
Abstract
Subject headings
Close
- Research on solvent chemistry, particularly for halide perovskite intermediates, has been advancing the development of perovskite solar cells (PSCs) toward commercial applications. A predictive understanding of solvent effects on the perovskite formation is thus essential. This work systematically discloses the relationship among the basicity of solvents, solvent-contained intermediate structures, and intermediate-to-perovskite alpha-FAPbI(3) evolutions. Depending on their basicity, solvents exhibit their own favorite bonding selection with FA(+) or Pb2+ cations by forming either hydrogen bonds or coordination bonds, resulting in two different kinds of intermediate structures. While both intermediates can be evolved into alpha-FAPbI(3) below the delta-to-alpha thermodynamic temperature, the hydrogen-bond-favorable kind could form defect-less alpha-FAPbI(3) via sidestepping the break of strong coordination bonds. The disclosed solvent gaming mechanism guides the solvent selection for fabricating high-quality perovskite films and thus high-performance PSCs and modules.
Subject headings
- NATURVETENSKAP -- Kemi -- Materialkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Materials Chemistry (hsv//eng)
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
Publication and Content Type
- ref (subject category)
- art (subject category)
Find in a library
- ACS CENTRAL SCIENCE (Search for host publication in LIBRIS)
To the university's database
- 1 of 1
- Previous record
- Next record
- To hitlist
Find more in SwePub
- By the author/editor
- Huang, Xiaofeng
- Deng, Guocheng
- Zhan, Shaoqi
- Cao, Fang
- Cheng, Fangwen
- Yin, Jun
- show more...
- Li, Jing
- Wu, Binghui
- Zheng, Nanfeng
- show less...
- About the subject
-
- NATURAL SCIENCES
- NATURAL SCIENCES
- and Chemical Science ...
- and Materials Chemis ...
-
- NATURAL SCIENCES
- NATURAL SCIENCES
- and Chemical Science ...
- and Physical Chemist ...
- Articles in the publication
- ACS CENTRAL SCIE ...
- By the university
- Uppsala University
Search outside SwePub
- Extend your search to:
- Google Book Search
- Google Scholar
Kungliga biblioteket hanterar dina personuppgifter i enlighet med EU:s dataskyddsförordning (2018), GDPR. Läs mer om hur det funkar här.
Så här hanterar KB dina uppgifter vid användning av denna tjänst.
- Copyright © LIBRIS - National Library Systems
- LIBRIS.kb.se
