Search: id:"swepub:oai:DiVA.org:uu-531617" >
Hydrophilic Cocryst...
Hydrophilic Cocrystals with Water Switched Luminescence
-
- Gao, Lei (author)
- Donghua Univ, Coll Chem & Chem Engn, State Key Lab Modificat Chem Fibers & Polymer Mat, Minist Educ,Sci & Technol Ecotext, Shanghai 201620, Peoples R China.;Wuzhou Univ, Coll Food & Pharmaceut Engn, Wuzhou 543000, Peoples R China.
-
- Baryshnikov, Glib (author)
- Linköpings universitet,Laboratoriet för organisk elektronik,Tekniska fakulteten,Linköping Univ, Dept Sci & Technol, Lab Organ Elect, SE-60174 Norrköping, Sweden.;Bohdan Khmelnytsky Natl Univ, Dept Chem & Nanomat Sci, UA-18031 Cherkassy, Ukraine.
-
- Ali, Amjad (author)
- Linköpings universitet,Laboratoriet för organisk elektronik,Tekniska fakulteten,Linköping Univ, Dept Sci & Technol, Lab Organ Elect, SE-60174 Norrköping, Sweden.
-
show more...
-
- Kuklin, Artem V. (author)
- Uppsala universitet,Institutionen för fysik och astronomi,Uppsala Univ, Sweden
-
- Qian, Cheng (author)
- Donghua Univ, Coll Chem & Chem Engn, State Key Lab Modificat Chem Fibers & Polymer Mat, Minist Educ,Sci & Technol Ecotext, Shanghai 201620, Peoples R China.
-
- Zhang, Xianrui (author)
- Wuzhou Univ, Coll Food & Pharmaceut Engn, Wuzhou 543000, Peoples R China.
-
- Chen, Fengkun (author)
- Donghua Univ, Coll Chem & Chem Engn, State Key Lab Modificat Chem Fibers & Polymer Mat, Minist Educ,Sci & Technol Ecotext, Shanghai 201620, Peoples R China.
-
- Yi, Tao (author)
- Donghua Univ, Coll Chem & Chem Engn, State Key Lab Modificat Chem Fibers & Polymer Mat, Minist Educ,Sci & Technol Ecotext, Shanghai 201620, Peoples R China.
-
- Wu, Hongwei (author)
- Donghua Univ, Coll Chem & Chem Engn, State Key Lab Modificat Chem Fibers & Polymer Mat, Minist Educ,Sci & Technol Ecotext, Shanghai 201620, Peoples R China.
-
show less...
-
Donghua Univ, Coll Chem & Chem Engn, State Key Lab Modificat Chem Fibers & Polymer Mat, Minist Educ,Sci & Technol Ecotext, Shanghai 201620, Peoples R China;Wuzhou Univ, Coll Food & Pharmaceut Engn, Wuzhou 543000, Peoples R China. Laboratoriet för organisk elektronik (creator_code:org_t)
- John Wiley & Sons, 2024
- 2024
- English.
-
In: Angewandte Chemie International Edition. - : John Wiley & Sons. - 1433-7851 .- 1521-3773. ; 63:8
- Related links:
-
https://urn.kb.se/re...
-
show more...
-
https://doi.org/10.1...
-
https://urn.kb.se/re...
-
show less...
Abstract
Subject headings
Close
- Utilizing water molecules to regulate the luminescence properties of solid materials is highly challenging. Herein, we develop a strategy to produce water-triggered luminescence-switching cocrystals by coassembling hydrophilic donors with electron-deficient acceptors, where 1,2,4,5-Tetracyanobenzene (TCNB) was used as the electron acceptor and pyridyl benzimidazole derivatives were used as the electron donors enabling multiple hydrogen-bonds. Two cocrystals, namely 2PYTC and 4PYTC were obtained and showed heat-activated emission, and such emission could be quenched or weakened by adding water molecules. The cocrystal structure exhibited the donor molecule that can form multiple hydro bonds with water and acceptor molecules due to the many nitrogen atoms of them. The analyses of the photophysical data, powder X-ray diffraction, and other data confirmed the reversible fluorescence "on-off" effects were caused by eliminating and adding water molecules in the crystal lattice. The density functional theory calculations indicate that the vibration of the O-H bond of water molecules in the cocrystal can absorb the excitation energy and suppress fluorescence. Furthermore, the obtained cocrystals also showed temperature, humidity, and H+/NH4+ responsive emission behavior, which allows their applications as thermal and humidity sensors, and multiple information encryptions. This research paves the way for preparing intelligent hydrophilic organic cocrystal luminescent materials. Hydrophilic donors with electron-deficient acceptors were coassembled to achieve luminescence-switching cocrystals triggered by water molecules. The obtained cocrystals show a strong water absorption ability and excellent fluorescence properties. The emission of cocrystals can be reversibly switched by heating and water. Finally, the obtained cocrystals show potential applications in temperature-humidity and acid-base responses.+image
Subject headings
- MEDICIN OCH HÄLSOVETENSKAP -- Hälsovetenskap -- Annan hälsovetenskap (hsv//swe)
- MEDICAL AND HEALTH SCIENCES -- Health Sciences -- Other Health Sciences (hsv//eng)
- NATURVETENSKAP -- Kemi -- Oorganisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)
Keyword
- Charge Transfer
- Cocrystal
- Hydrogen Bonds
- Luminescent Switching
- Supramolecular Chemistry
Publication and Content Type
- ref (subject category)
- art (subject category)
Find in a library
To the university's database