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The role of molecul...
The role of molecular polarity in cluster local structure studied by photoelectron spectroscopy
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- Rosso, Aldana (author)
- Lund University,Lunds universitet,Uppsala universitet,Fysik V,MAX IV-laboratoriet,MAX IV Laboratory
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- Rander, Torbjörn (author)
- Uppsala universitet,Fysik V
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- Bergersen, Henrik (author)
- Uppsala universitet,Fysik V
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- Lindblad, Andreas (author)
- Uppsala universitet,Fysik V
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- Lundwall, Marcus (author)
- Uppsala universitet,Fysik V
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- Svensson, Svante (author)
- Uppsala universitet,Fysik V
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- Tchaplyguine, Maxim (author)
- Lund University,Lunds universitet,Uppsala universitet,Fysik V,MAX IV-laboratoriet,MAX IV Laboratory
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- Öhrwall, Gunnar (author)
- Lund University,Lunds universitet,Uppsala universitet,Fysik V,MAX IV-laboratoriet,MAX IV Laboratory
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Saethre, Leif (author)
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- Björneholm, Olle (author)
- Uppsala universitet,Molekyl- och kondenserade materiens fysik
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(creator_code:org_t)
- Elsevier BV, 2007
- 2007
- English.
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In: Chemical Physics Letters. - : Elsevier BV. - 0009-2614 .- 1873-4448. ; 435:1-3, s. 79-83
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http://dx.doi.org/10...
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https://urn.kb.se/re...
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Abstract
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- We have studied the spatial structure and electronic levels of clusters of the molecule CH3Br to investigate the effects of molecular polarity on these properties. Analysis of the core level photoelectron spectra of initially neutral CH3Br clusters shows that the C 1 s-1 state has a 30% larger binding energy shift between free molecules and clusters than the Br 3d-1 state. This difference is attributed to an anti-parallel packing of the molecules induced by the polar character of bromomethane. The results obtained from the analysis of valence cluster spectra also support the proposed structure.
Subject headings
- NATURVETENSKAP -- Fysik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences (hsv//eng)
Keyword
- Physics
- Fysik
Publication and Content Type
- ref (subject category)
- art (subject category)
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- By the author/editor
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Rosso, Aldana
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Rander, Torbjörn
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Bergersen, Henri ...
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Lindblad, Andrea ...
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Lundwall, Marcus
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Svensson, Svante
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show more...
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Tchaplyguine, Ma ...
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Öhrwall, Gunnar
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Saethre, Leif
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Björneholm, Olle
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show less...
- About the subject
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Physical Science ...
- Articles in the publication
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Chemical Physics ...
- By the university
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Uppsala University
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Lund University