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Electronic Structure of Core-excited and Core-ionized Methyl Oxirane
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- Piancastelli, Maria Novella (author)
- Uppsala universitet,Fysik V
- Prümper, G. (author)
- Lischke, T. (author)
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- Liu, X. J (author)
- Fukuzawa, H. (author)
- Hoshino, M. (author)
- Tanaka, T. (author)
- Tanaka, H. (author)
- Harries, J. (author)
- Tamenori, Y. (author)
- Ueda, K. (author)
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- (creator_code:org_t)
- Elsevier BV, 2007
- 2007
- English.
- In: Journal of Electron Spectroscopy and Related Phenomena. - : Elsevier BV. - 0368-2048 .- 1873-2526. ; 156, s. 259-264
- Journal article (peer-reviewed)
Abstract
Subject headings
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- We report a detailed analysis of the electronic structure of methyl oxirane, including core-level photoelectron spectroscopy, X-ray absorption at both C and O K-shells, resonant Auger and normal Auger spectroscopy. The X-ray absorption spectra (XAS) around the C K-edge can be easily interpreted on the ground of the chemical shift between the carbon atoms with different chemical environments. The X-ray absorption data around the O K-edge are quite structureless, hinting for a likely fragmentation process (possibly implying a ring-opening reaction). In resonant Auger spectra obtained after excitation below both the C 1s and O 1s ionization thresholds we notice a predominance of spectator decay implying a strong mixing between empty molecular orbitals and Rydberg states.
Subject headings
- NATURVETENSKAP -- Fysik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences (hsv//eng)
Keyword
- Auger decay
- X-ray
- Fragmentation
- Chiral
- Physics
- Fysik
Publication and Content Type
- ref (subject category)
- art (subject category)
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- Prümper, G.
- Lischke, T.
- Liu, X. J
- Fukuzawa, H.
- Hoshino, M.
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- Tanaka, T.
- Tanaka, H.
- Harries, J.
- Tamenori, Y.
- Bao, Zhuo
- Travnikova, Oksa ...
- Céolin, Denis
- Ueda, K.
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- Uppsala University
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