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Acyl Radicals from Aromatic Carboxylic Acids by Means of Visible-Light Photoredox Catalysis.

Bergonzini, Giulia, 1985 (author)
Gothenburg University,Göteborgs universitet,Institutionen för kemi och molekylärbiologi,Department of Chemistry and Molecular Biology
Cassani, Carlo, 1984 (author)
Gothenburg University,Göteborgs universitet,Institutionen för kemi och molekylärbiologi,Department of Chemistry and Molecular Biology
Wallentin, Carl Johan, 1978 (author)
Gothenburg University,Göteborgs universitet,Institutionen för kemi och molekylärbiologi,Department of Chemistry and Molecular Biology
 (creator_code:org_t)
2015-09-25
2015
English.
In: Angewandte Chemie (International ed. in English). - : Wiley. - 1521-3773. ; 54:47, s. 14066-14069
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • Simple and abundant carboxylic acids have been used as acyl radical precursor by means of visible-light photoredox catalysis. By the transient generation of a reactive anhydride intermediate, this redox-neutral approach offers a mild and rapid entry to high-value heterocyclic compounds without the need of UV irradiation, high temperature, high CO pressure, tin reagents, or peroxides.

Subject headings

NATURVETENSKAP  -- Kemi (hsv//swe)
NATURAL SCIENCES  -- Chemical Sciences (hsv//eng)

Keyword

acyl radicals; acylarylation; carboxylic acids; oxindoles; photoredox catalysis

Publication and Content Type

ref (subject category)
art (subject category)

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