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Radiative cooling of cationic carbon clusters, CN+, N=8,10,13-16
- Chen, Fuqiang (author)
- Kono, Naoko (author)
- Suzuki, R. (author)
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- Furukawa, Takeshi (author)
- Tanuma, H. (author)
- Ferrari, Piero (author)
- Azuma, Toshiuki (author)
- Shiromaru, Haruo (author)
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- (creator_code:org_t)
- 2019
- 2019
- English.
- In: Physical Chemistry Chemical Physics - PCCP. - : Royal Society of Chemistry (RSC). - 1463-9076 .- 1463-9084. ; 21, s. 1587-1596
- Journal article (peer-reviewed)
Abstract
Subject headings
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- The radiative cooling of highly excited carbon cluster cations of sizes N = 8, 10, 13–16 has been studied in an electrostatic storage ring. The cooling rate constants vary with cluster size from a maximum at N = 8 of 2.6 × 104 s−1 and a minimum at N = 13 of 4.4 × 103 s−1. The high rates indicate that photon emission takes place from electronically excited ions, providing a strong stabilizing cooling of the molecules.
Subject headings
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
- NATURVETENSKAP -- Fysik -- Atom- och molekylfysik och optik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Atom and Molecular Physics and Optics (hsv//eng)
Keyword
- Carbon clusters
- thermal radiation
- recurrent fluorescence
Publication and Content Type
- ref (subject category)
- art (subject category)
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- Kono, Naoko
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- Shiromaru, Haruo
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- University of Gothenburg
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