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Signature of cluste...
Signature of cluster isomers in photodissociation experiments
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Vogel, M. (author)
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- Hansen, Klavs, 1958 (author)
- Gothenburg University,Göteborgs universitet,Institutionen för fysik (GU),Department of Physics (GU)
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Schweikhard, L. (author)
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(creator_code:org_t)
- Elsevier BV, 2004
- 2004
- English.
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In: Int.J.Mass Spectrom.. - : Elsevier BV. - 1387-3806. ; 233, s. 117-123
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http://physics.gu.se...
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https://doi.org/10.1...
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Abstract
Subject headings
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- The unrecognized presence of structure isomers in mass-selected cluster ensembles may obstruct investigations of the systems’ intrinsic properties, since isomers differ not only in geometry, but also in other important properties. By the same token isomers are very interesting objects in the detailed study of atomic clusters. In the present work, different scenarios of isomeric coexistence are presented. They vary in the relative values of the interconversion barrier and the dissociation energies. For some idealized cases the possibility of a distinction of isomers by photodissociation experiments is discussed. In favorable situations isomeric structures may even be selected.
Subject headings
- NATURVETENSKAP -- Fysik -- Atom- och molekylfysik och optik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Atom and Molecular Physics and Optics (hsv//eng)
- NATURVETENSKAP -- Fysik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences (hsv//eng)
Keyword
- Fragmentation
- Nanoparticles
- Charged clusters
- Isomers
Publication and Content Type
- ref (subject category)
- art (subject category)
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