id:"swepub:oai:lup.lub.lu.se:11c63ac1-e118-4088-92b1-7be28347df1b"
Search: id:"swepub:oai:lup.lub.lu.se:11c63ac1-e118-4088-92b1-7be28347df1b" > Catalytic Oxidation...
- 1 of 1
- Previous record
- Next record
- To hitlist
Catalytic Oxidation of Alkanes and Alkenes by H2O2 with a mu-Oxido Diiron(III) Complex as Catalyst/Catalyst Precursor
-
- Das, Biswanath (author)
- Lund University,Lunds universitet,Kemisk fysik,Enheten för fysikalisk och teoretisk kemi,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Chemical Physics,Physical and theoretical chemistry,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
- Al-Hunaiti, Afnan (author)
- Haukka, Matti (author)
- show more...
- Demeshko, Serhiy (author)
- Meyer, Steffen (author)
- Shteinman, Albert A. (author)
- Meyer, Franc (author)
- Repo, Timo (author)
- show less...
- (creator_code:org_t)
- 2015-07-17
- 2015
- English.
- In: European Journal of Inorganic Chemistry. - : Wiley. - 1099-0682 .- 1434-1948. ; :21, s. 3590-3601
- Journal article (peer-reviewed)
Abstract
Subject headings
Close
- A new mu-oxo diiron(III) complex of the lithium salt of the pyridine-based unsymmetrical ligand 3-[(3-{[bis(pyridin-2-ylmethyl)amino]methyl}-2-hydroxy-5-methylbenzyl)(pyridin2-ylmethyl)amino] propanoate (LiDPCPMPP), [Fe-2(mu-O)(LiDPCPMPP)(2)](ClO4)(2), has been synthesized and characterized. The ability of the complex to catalyze oxidation of several alkanes and alkenes has been investigated by using CH3COOH/H2O2 (1:1) as an oxidative system. Moderate activity in cyclohexane oxidation (TOF = 33 h(-1)) and good activity in cyclohexene oxidation (TOF = 72 h(-1)) were detected. Partial retention of configuration (RC = 53%) in cis- and trans-1,2-dimethylcyclohexane oxidation, moderate 3 degrees/2 degrees selectivity (4.1) in adamantane oxidation, and the observation of a relatively high kinetic isotope effect for cyclohexane oxidation (KIE = 3.27) suggest partial metal-based oxidation, probably in tandem with free-radical oxidation. Low-temperature UV/Vis spectroscopy and mass spectrometric studies in the rapid positive detection mode indicate the formation of a transient peroxido species, [Fe-2(O)(O-2)-(LiDPCPMPP)(2)](2+), which might be an intermediate in the metal-based component of the oxidation process.
Subject headings
- NATURVETENSKAP -- Kemi -- Oorganisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)
Keyword
- Monooxygenases
- Iron
- Lithium
- Oxidation
- Homogeneous catalysis
Publication and Content Type
- art (subject category)
- ref (subject category)
Find in a library
- European Journal of Inorganic Chemistry (Search for host publication in LIBRIS)
To the university's database
- 1 of 1
- Previous record
- Next record
- To hitlist
Find more in SwePub
- By the author/editor
- Das, Biswanath
- Al-Hunaiti, Afna ...
- Haukka, Matti
- Demeshko, Serhiy
- Meyer, Steffen
- Shteinman, Alber ...
- show more...
- Meyer, Franc
- Repo, Timo
- Nordlander, Ebbe
- show less...
- About the subject
-
- NATURAL SCIENCES
- NATURAL SCIENCES
- and Chemical Science ...
- and Inorganic Chemis ...
- Articles in the publication
- European Journal ...
- By the university
- Lund University
Search outside SwePub
- Extend your search to:
- Google Book Search
- Google Scholar
Kungliga biblioteket hanterar dina personuppgifter i enlighet med EU:s dataskyddsförordning (2018), GDPR. Läs mer om hur det funkar här.
Så här hanterar KB dina uppgifter vid användning av denna tjänst.
- Copyright © LIBRIS - National Library Systems
- LIBRIS.kb.se
