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Multi-component chemical analysis of gas mixtures using a continuously tuneable lidar system

Weibring, Petter (author)
Lund University,Lunds universitet,Atomfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Atomic Physics,Department of Physics,Departments at LTH,Faculty of Engineering, LTH
Abrahamsson, Christoffer (author)
Lund University,Lunds universitet,Atomfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Atomic Physics,Department of Physics,Departments at LTH,Faculty of Engineering, LTH
Sjöholm, Mikael (author)
Lund University,Lunds universitet,Atomfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Atomic Physics,Department of Physics,Departments at LTH,Faculty of Engineering, LTH
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Smith, JN (author)
Edner, Hans (author)
Lund University,Lunds universitet,Atomfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Atomic Physics,Department of Physics,Departments at LTH,Faculty of Engineering, LTH
Svanberg, Sune (author)
Lund University,Lunds universitet,Atomfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Atomic Physics,Department of Physics,Departments at LTH,Faculty of Engineering, LTH
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 (creator_code:org_t)
2004-09-01
2004
English.
In: Applied Physics B. - : Springer Science and Business Media LLC. - 0946-2171 .- 1432-0649. ; 79:4, s. 525-530
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • Differential absorption lidar (DIAL) measurements are usually made on single compounds by alternately switching the wavelength between on and off a resonance line. The selection of more than two wavelengths is a mathematical necessity for simultaneous measurement of multiple species or for resolving interference effects between a compound of interest and a background gas such as water vapour or carbon dioxide. This is especially true in the mid-IR region, where many hydrocarbon compounds have important spectral features. We present a method for remote measurement of gas mixtures in the mid-IR region based on a newly developed fast-switching, frequency-agile optical parametric oscillator lidar transmitter. A multivariate statistical procedure has also been applied for this system, which combines a genetic algorithm for wavelength selection with a partial least squares method for identifying individual compounds from their combined absorption spectrum. A calibration transfer is performed for compounds of interest using reference spectra from an absorption spectra database. Both indoor absorption cell measurements and outdoor remote range resolved measurements of hydrocarbon mixtures were performed to explore the performance of the method.

Subject headings

NATURVETENSKAP  -- Fysik -- Atom- och molekylfysik och optik (hsv//swe)
NATURAL SCIENCES  -- Physical Sciences -- Atom and Molecular Physics and Optics (hsv//eng)

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