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Systematic studies of highly excited Rydberg states in ions with two valance electrons
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- Andersson, Martin (author)
- Lund University,Lunds universitet,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Department of Physics,Departments at LTH,Faculty of Engineering, LTH
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- Brage, Tomas (author)
- Lund University,Lunds universitet,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Department of Physics,Departments at LTH,Faculty of Engineering, LTH
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- Hutton, Roger (author)
- Lund University,Lunds universitet,Astronomi - Genomgår omorganisation,Institutionen för astronomi och teoretisk fysik - Genomgår omorganisation,Naturvetenskapliga fakulteten,Lund Observatory - Undergoing reorganization,Department of Astronomy and Theoretical Physics - Undergoing reorganization,Faculty of Science
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- Kink, Ilmar (author)
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- (creator_code:org_t)
- 2006-06-05
- 2006
- English.
- In: Journal of Physics B: Atomic, Molecular and Optical Physics. - : IOP Publishing. - 0953-4075 .- 1361-6455. ; 39:12, s. 2815-2826
- Journal article (peer-reviewed)
Abstract
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- A method, based on the multiconfiguration Hartree-Fock approach, for ab initio calculations of Rydberg states has been developed. The method has been tested for a number of highly excited Rydberg states, with quantum numbers l = 4 - 8 and n <= 9, in Mg-like and Be-like ions. The results are compared with Hartree-Fock calculations to investigate the influence of correlation and, to a lesser extent, relativistic effects. The theoretical spectra for Cl VI and the lifetimes of the 2s6g-levels in O V are in excellent agreement with experimental results. More limited calculations have also been done for some Rydberg series in S V and Ar VII to illustrate the changing influence of perturbers along the isoelectronic sequence. The difficulties of using isoelectronic extrapolation/interpolation in making predictions for this kind of systems are discussed.
Subject headings
- NATURVETENSKAP -- Fysik -- Atom- och molekylfysik och optik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Atom and Molecular Physics and Optics (hsv//eng)
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