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Collisional properties of trapped cold chromium atoms

Pavlovic, Z (author)
Roos, Björn (author)
Lund University,Lunds universitet,Beräkningskemi,Enheten för fysikalisk och teoretisk kemi,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Computational Chemistry,Physical and theoretical chemistry,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
Cote, R (author)
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Sadeghpour, H R (author)
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 (creator_code:org_t)
2004
2004
English.
In: Physical Review A (Atomic, Molecular and Optical Physics). - 1050-2947. ; 69:3, s. 1-030701
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • We report on calculations of the elastic cross section and thermalization rate for collision between two maximally spin-polarized chromium atoms in the cold and ultracold regimes, relevant to buffer-gas and magneto-optical cooling. We calculate ab initio potential-energy curves for Cr-2 and the van der Waals coefficient C-6, and construct interaction potentials between two colliding Cr atoms. We explore the effect of shape resonances on the elastic cross section, and find that they dramatically affect the thermalization rate. Our calculated value for the s-wave scattering length is compared in magnitude with a recent measurement. We propose that a dip in the elastic rate coefficient could be experimentally exploited to obtain an accurate value for the scattering length.

Subject headings

NATURVETENSKAP  -- Kemi -- Teoretisk kemi (hsv//swe)
NATURAL SCIENCES  -- Chemical Sciences -- Theoretical Chemistry (hsv//eng)

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Pavlovic, Z
Roos, Björn
Cote, R
Sadeghpour, H R
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