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Solvent Exchange an...
Solvent Exchange and Complex Formation Reactions of Pd(II) in Aqueous Solution. Mechanistic Information from High Pressure Studies
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- Hellquist, Björn (author)
- Jönköping University,Mid Sweden University,HLK, Ämnesforskning
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- Elding, Lars Ivar (author)
- Lund University,Lunds universitet,Centrum för analys och syntes,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Centre for Analysis and Synthesis,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
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- Merbach, Andre E. (author)
- University of Lausanne
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- Ducommun, Yves (author)
- University of Lausanne
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- Helm, Lothar (author)
- University of Lausanne
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- van Eldik, Rudi (author)
- Witten/Herdecke University
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(creator_code:org_t)
- 2006-12
- 1990
- English.
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In: High Pressure Research. - : Informa UK Limited. - 1477-2299 .- 0895-7959. ; 1990:5, s. 672-674
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Abstract
Subject headings
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- High pressure NMR and stopped-flow techniques have been employed to study a series of water exchange and complex formation reactions of Pd(II) outlined in (1) and (2). The volumes of activation show an interesting correlation with the partial molar volume of the entering ligand and underline the operation of an associative substitution mechanism in all cases.
- High pressure NMR and stopped-flow techniques have been employed to study a series of water exchange and complex formation reactions of Pd(II) outlined in (1) and (2). The volumes of activation show an interesting correlation with the partial molar volume of the entering ligand and underline the operation of an associative substitution mechanism in all cases.
Subject headings
- NATURVETENSKAP -- Kemi -- Oorganisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
Keyword
- Solvent exchange
- Complex formatioon
- Palladium(II)
- Volume of activation
- Associative reactions
- High pressure stopped-flow
- High pressure NMR
- High Pressure NMR
- High pressure stopped-Flow
- Activation volume
- Reaction mechanism
- Associative mechanism
Publication and Content Type
- art (subject category)
- ref (subject category)
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