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Bayesian determinat...
Bayesian determination of the effect of a deep eutectic solvent on the structure of lipid monolayers
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- McCluskey, Andrew R. (author)
- Diamond Light Source,University of Bath
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- Sanchez-Fernandez, Adrian (author)
- European Spallation Source ESS AB,University of Bath
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- Edler, Karen J. (author)
- University of Bath
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- Parker, Stephen C. (author)
- University of Bath
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- Jackson, Andrew J. (author)
- Lund University,Lunds universitet,Fysikalisk kemi,Enheten för fysikalisk och teoretisk kemi,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Physical Chemistry,Physical and theoretical chemistry,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH,European Spallation Source ESS AB
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- Campbell, Richard A. (author)
- Institut Laue Langevin,University of Manchester
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- Arnold, Thomas (author)
- University of Bath,Diamond Light Source,Rutherford Appleton Laboratory,European Spallation Source ESS AB
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(creator_code:org_t)
- 2019
- 2019
- English 9 s.
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In: Physical Chemistry Chemical Physics. - : Royal Society of Chemistry (RSC). - 1463-9076 .- 1463-9084. ; 21:11, s. 6133-6141
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Abstract
Subject headings
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- In this work, we present the first example of the self-assembly of phospholipid monolayers at the interface between air and an ionic solvent. Deep eutectic solvents are a novel class of environmentally friendly, non-aqueous, room temperature liquids with tunable properties, that have wide-ranging potential applications and are capable of promoting the self-assembly of surfactant molecules. We use a chemically-consistent Bayesian modelling of X-ray and neutron reflectometry measurements to show that these monolayers broadly behave as they do on water. This method allows for the monolayer structure to be determined, alongside the molecular volumes of the individual monolayer components, without the need for water-specific constraints to be introduced. Furthermore, using this method we are able to better understand the correlations present between parameters in the analytical model. This example of a non-aqueous phospholipid monolayer has important implications for the potential uses of these solvents and for our understanding of how biomolecules behave in the absence of water.
Subject headings
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
Publication and Content Type
- art (subject category)
- ref (subject category)
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