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Mechanism of Electrochemical Delamination of Two-Dimensional Materials from Their Native Substrates by Bubbling

Sun, Jie, 1977 (author)
Chalmers tekniska högskola,Chalmers University of Technology
Fan, X. (author)
Beijing University of Technology
Guo, W. L. (author)
Beijing University of Technology
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Liu, Lihui, 1985 (author)
Chalmers tekniska högskola,Chalmers University of Technology
Liu, X. (author)
Beijing University of Technology
Deng, J. (author)
Beijing University of Technology
Xu, C. (author)
Beijing University of Technology
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 (creator_code:org_t)
2015-12-16
2015
English.
In: Sensors. - : MDPI AG. - 1424-8220. ; 15:12, s. 31811-31820
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • A capacitor-based circuit model is proposed to explain the electrochemical delamination of two-dimensional materials from their native substrates where produced gas bubbles squeeze into the interface. The delamination is actually the electric breakdown of the capacitor formed between the solution and substrate. To facilitate the procedure, the backside of the ubstrate has to be shielded so that the capacitor breakdown voltage can be reached. The screening effect can be induced either by nonreactive ions around the electrode or, more effectively, by an undetachable insulator. This mechanism serves as a guideline for the surface science and applications involving the bubbling delamination.

Subject headings

NATURVETENSKAP  -- Kemi -- Oorganisk kemi (hsv//swe)
NATURAL SCIENCES  -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)

Keyword

electrochemical bubbling transfer
chemical vapor deposition
graphene

Publication and Content Type

art (subject category)
ref (subject category)

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