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Columnar Formation in Sodium Triphenylacetate
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- Henriques, M. S. C. (author)
- Universidade de Coimbra,University of Coimbra
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- David, M. A. (author)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Ramos Silva, M. (author)
- Universidade de Coimbra,University of Coimbra
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- (creator_code:org_t)
- 2014-10-18
- 2014
- English.
- In: Journal of Chemical Crystallography. - : Springer Science and Business Media LLC. - 1074-1542 .- 1572-8854. ; 44:11-12, s. 543-547
- Journal article (peer-reviewed)
Abstract
Subject headings
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- A new sodium salt, sodium triphenylacetate has been synthesized and characterized by single-crystal X-ray diffraction: triclinic, P-1 with a = 8.3846(2) angstrom, b = 13.5992(3) angstrom, c = 15.5288(3) angstrom, a = 76.7270(11)degrees, b = 74.4500(11)degrees, c = 84.7410(13)degrees, M-W = 656.65, V = 1659.42(6) angstrom(3), Z = 2. The triphenylacetic molecules bridge the metallic ions forming an infinite columnar structure. Calorimetric data does not support the existence of a mesophase induced by temperature.
Subject headings
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Keyword
- Sodium salt
- Hydrogen bonds
- Triphenylacetic acid
- Columnar structure
- Flexible molecule
Publication and Content Type
- art (subject category)
- ref (subject category)
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- Martin-Ramos, P.
- Maria, T. M. R.
- Paixao, J. A.
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