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On the mechanism of enhanced photocatalytic activity of composite TiO(2)/carbon nanofilms

Sellappan, Raja, 1981 (author)
Chalmers tekniska högskola,Chalmers University of Technology
Galeckas, A. (author)
Universitetet i Oslo,University of Oslo
Venkatachalapathy, V. (author)
Universitetet i Oslo,University of Oslo
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Kuznetsov, A. Y. (author)
Universitetet i Oslo,University of Oslo
Chakarov, Dinko, 1955 (author)
Chalmers tekniska högskola,Chalmers University of Technology
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 (creator_code:org_t)
Elsevier BV, 2011
2011
English.
In: Applied Catalysis B: Environmental. - : Elsevier BV. - 0926-3373 .- 1873-3883. ; 106:3-4, s. 337-342
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • In the search for the origin of the enhanced photocatalytic activity of composite TiO(2)-carbon systems, we have fabricated and analyzed well-defined model samples consisting of anatase and graphitic carbon with and without modifying the interface between them by a thin SiO(2) space layer. The films with a TiO(2)/C interface show noticeably lower photoluminescence intensity and shorter carrier life times compared to single TiO(2) films with the same thickness and composition. The stronger non-radiative recombination is mainly assigned to charge carrier leakage (transfer) at the interface between TiO(2) nanocrystallites and the carbon film. (C) 2011 Elsevier B.V. All rights reserved.

Subject headings

NATURVETENSKAP  -- Fysik (hsv//swe)
NATURAL SCIENCES  -- Physical Sciences (hsv//eng)

Keyword

carriers lifetime
excitation
anatase tio2
Photocatalysis
photoluminescence
Charge transfer mechanism
TiO(2)-carbon composites
arrays
Charge
carbon
spectroscopy
luminescence
water
Photoluminescence

Publication and Content Type

art (subject category)
ref (subject category)

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