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Assembly of Chiral ...
Assembly of Chiral Amino-Acids at Surfaces from a Single Molecule Perspective: Proline on Cu(110)
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- Forster, M. (author)
- University of Liverpool
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- Dyer, M. S. (author)
- University of Liverpool
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- Persson, Mats, 1954 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Raval, R. (author)
- University of Liverpool
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(creator_code:org_t)
- 2011-01-21
- 2011
- English.
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In: Topics in Catalysis. - : Springer Science and Business Media LLC. - 1572-9028 .- 1022-5528. ; 54:1-4, s. 13-19
- Related links:
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http://dx.doi.org/10...
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https://research.cha...
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https://doi.org/10.1...
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Abstract
Subject headings
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- We present a molecule-by-molecule mapping of an amino-acid monolayer on a Cu(110) surface in which individual molecular configuration, bonding and adsorption footprints are identified. This detailed mapping provides direct evidence that the (4 x 2) structures of enantiopure and racemic proline are governed by a strict heterochiral adsorption footprint template. For the racemic system this has an interesting consequence, namely that it leads to a 2-D random solid solution, a situation that is rarely encountered in 3-D.
Subject headings
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Keyword
- Scanning tunnelling microscopy
- Chiral
- Random solid solutions
- surfaces
- Footprints
- Amino acids
Publication and Content Type
- art (subject category)
- ref (subject category)
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