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Assembly of Chiral Amino-Acids at Surfaces from a Single Molecule Perspective: Proline on Cu(110)

Forster, M. (author)
University of Liverpool
Dyer, M. S. (author)
University of Liverpool
Persson, Mats, 1954 (author)
Chalmers tekniska högskola,Chalmers University of Technology
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Raval, R. (author)
University of Liverpool
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 (creator_code:org_t)
2011-01-21
2011
English.
In: Topics in Catalysis. - : Springer Science and Business Media LLC. - 1572-9028 .- 1022-5528. ; 54:1-4, s. 13-19
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • We present a molecule-by-molecule mapping of an amino-acid monolayer on a Cu(110) surface in which individual molecular configuration, bonding and adsorption footprints are identified. This detailed mapping provides direct evidence that the (4 x 2) structures of enantiopure and racemic proline are governed by a strict heterochiral adsorption footprint template. For the racemic system this has an interesting consequence, namely that it leads to a 2-D random solid solution, a situation that is rarely encountered in 3-D.

Subject headings

NATURVETENSKAP  -- Kemi (hsv//swe)
NATURAL SCIENCES  -- Chemical Sciences (hsv//eng)

Keyword

Scanning tunnelling microscopy
Chiral
Random solid solutions
surfaces
Footprints
Amino acids

Publication and Content Type

art (subject category)
ref (subject category)

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Forster, M.
Dyer, M. S.
Persson, Mats, 1 ...
Raval, R.
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NATURAL SCIENCES
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Chalmers University of Technology

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