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LIBRIS Formathandbok  (Information om MARC21)
FältnamnIndikatorerMetadata
00003265naa a2200505 4500
001oai:DiVA.org:kth-21705
003SwePub
008100810s2002 | |||||||||||000 ||eng|
024a https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-217052 URI
024a https://doi.org/10.1016/S0010-938X(02)00015-X2 DOI
040 a (SwePub)kth
041 a engb eng
042 9 SwePub
072 7a ref2 swepub-contenttype
072 7a art2 swepub-publicationtype
100a Zhang, X. Y.4 aut
2451 0a Determination of instantaneous corrosion rates and runoff rates of copper from naturally patinated copper during continuous rain events
264 1c 2002
338 a print2 rdacarrier
500 a QC 20100525
520 a Instantaneous corrosion rates of naturally patinated copper of varying age (16 months, 138 and 145 years) have been determined during continuous rain events in the laboratory with electrochemical impedance spectroscopy using a two-electrode cell. The two-electrode cell was found to yield the same information in bulk rainwater as a conventional three-electrode cell. Relatively constant corrosion rates, between 0.2 and 0.6 mum/y, were determined for samples having a two-layer structure with an inner brownish layer of cuprous oxide and an outer greenish layer of basic copper salts (138, 145 years). Samples with cuprous oxide as the dominating phase of the patina (16 months) showed higher and somewhat increasing corrosion rates during a rain event (from 0.6 to 1.2 mum/y). During a continuous rain event, corrosion rates were found to be approximately 10 (brownish patina) and 25 times (greenish patina) lower than corresponding instantaneous runoff rates. The first flush phenomena of the runoff process, with an increased concentration during first flush and a relatively constant concentration during steady state, was indirectly seen as an increase in solution conductivity during the first rain volume followed by relative constant value. The contribution of the concentration in the first flush to the total annual runoff rate was significant for panels having a greenish layer (138, 145 years) whereas it was negligible for panels having a brownish layer (16 months).
653 a atmospheric corrosion
653 a copper
653 a corrosion rate
653 a runoff rate
653 a artificial rain
653 a electrochemical impedance spectroscopy
653 a electrochemical impedance spectroscopy
653 a atmospheric corrosion
653 a electrolyte layers
653 a galvanized steel
653 a ac-impedance
653 a thin
653 a media
653 a roofs
653 a iron
653 a zinc
700a He, W. L.4 aut
700a Odnevall Wallinder, Ingeru KTH,Materialvetenskap4 aut0 (Swepub:kth)u1ngonee
700a Pan, Jinshanu KTH,Materialvetenskap4 aut0 (Swepub:kth)u17ks6cf
700a Leygraf, Christoferu KTH,Materialvetenskap4 aut0 (Swepub:kth)u1itk7c9
710a KTHb Materialvetenskap4 org
773t Corrosion Scienceg 44:9, s. 2131-2151q 44:9<2131-2151x 0010-938Xx 1879-0496
8564 8u https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-21705
8564 8u https://doi.org/10.1016/S0010-938X(02)00015-X

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