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Search: onr:"swepub:oai:DiVA.org:kth-246249" > Biocatalysis for te...

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LIBRIS Formathandbok  (Information om MARC21)
FältnamnIndikatorerMetadata
00003118naa a2200433 4500
001oai:DiVA.org:kth-246249
003SwePub
008190402s2019 | |||||||||||000 ||eng|
024a https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-2462492 URI
024a https://doi.org/10.1515/znc-2018-01992 DOI
040 a (SwePub)kth
041 a engb eng
042 9 SwePub
072 7a ref2 swepub-contenttype
072 7a art2 swepub-publicationtype
100a Farhat, Wissamu KTH,Ytbehandlingsteknik,Science for Life Laboratory, SciLifeLab4 aut0 (Swepub:kth)u1695ok5
2451 0a Biocatalysis for terpene-based polymers
264 c 2019-02-21
264 1b WALTER DE GRUYTER GMBH,c 2019
338 a print2 rdacarrier
500 a QC 20190402
520 a Accelerated generation of bio-based materials is vital to replace current synthetic polymers obtained from petroleum with more sustainable options. However, many building blocks available from renewable resources mainly contain unreactive carbon-carbon bonds, which obstructs their efficient polymerization. Herein, we highlight the potential of applying biocatalysis to afford tailored functionalization of the inert carbocyclic core of multicyclic terpenes toward advanced materials. As a showcase, we unlock the inherent monomer reactivity of norcamphor, a bicyclic ketone used as a monoterpene model system in this study, to afford polyesters with unprecedented backbones. The efficiencies of the chemical and enzymatic Baeyer-Villiger transformation in generating key lactone intermediates are compared. The concepts discussed herein are widely applicable for the valorization of terpenes and other cyclic building blocks using chemoenzymatic strategies.
650 7a NATURVETENSKAPx Kemix Polymerkemi0 (SwePub)104062 hsv//swe
650 7a NATURAL SCIENCESx Chemical Sciencesx Polymer Chemistry0 (SwePub)104062 hsv//eng
653 a biocatalysis
653 a biopolymers
653 a oxidoreductases
653 a polyesters
653 a terpenes
700a Stamm, Arneu KTH,Science for Life Laboratory, SciLifeLab,Ytbehandlingsteknik4 aut0 (Swepub:kth)u1m0o5w8
700a Robert-Monpate, Maximeu KTH,Ytbehandlingsteknik,Science for Life Laboratory, SciLifeLab,Ecole Super Chim Organ & Minerale, 1 Allee Reseau Jean Marie Buckmaster, F-60200 Compiegne, France4 aut0 (Swepub:kth)u1i93i9o
700a Biundo, Antoninou KTH,Science for Life Laboratory, SciLifeLab,Ytbehandlingsteknik4 aut0 (Swepub:kth)u1l1ee04
700a Syrén, Per-Olofu KTH,Science for Life Laboratory, SciLifeLab,Ytbehandlingsteknik4 aut0 (Swepub:kth)u1ewlo1g
710a KTHb Ytbehandlingsteknik4 org
773t Zeitschrift für Naturforschung C - A Journal of Biosciencesd : WALTER DE GRUYTER GMBHg 74:3-4, s. 90-99q 74:3-4<90-99x 0939-5075x 1865-7125
856u https://doi.org/10.1515/znc-2018-0199y Fulltext
856u https://www.degruyter.com/downloadpdf/journals/znc/74/3-4/article-p91.pdf
8564 8u https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-246249
8564 8u https://doi.org/10.1515/znc-2018-0199

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