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LIBRIS Formathandbok  (Information om MARC21)
FältnamnIndikatorerMetadata
00003787naa a2200421 4500
001oai:DiVA.org:kth-318666
003SwePub
008221031s2019 | |||||||||||000 ||eng|
024a https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-3186662 URI
024a https://doi.org/10.3390/nano90202312 DOI
040 a (SwePub)kth
041 a engb eng
042 9 SwePub
072 7a ref2 swepub-contenttype
072 7a art2 swepub-publicationtype
100a Michalska, Agnieszka4 aut
2451 0a Micro- and Nanostructured Polyaniline for Instant Identification of Metal Ions in Solution
264 c 2019-02-08
264 1b MDPI AG,c 2019
338 a print2 rdacarrier
500 a QC 20221031
520 a The unique properties of nanomaterials enable the creation new analytical devices. Polyaniline (PANI) micro- and nanofiber network, freestanding in the gap between two gold microelectrodes, has been used in a new nanodetector for metal ions in solutions. The gold electrodes were modified with the aid of alkanethiols, forming a self-assembled monolayer (SAM), which is able to block the ion current flow, but also to interact with metal ions when specific functional molecules are incorporated into the layer. The electric field of the trapped metal ions induces change of the electrical conductivity of polyaniline nanofibers in vicinity. A small injected sample (75 mu L) of a solution of salt (about 0.5 mu g of salt) was enough to induce a reproducible change in the electrical conductivity of polyaniline nano-network, which was registered as a function of time within 10-20 s. The response was proportional to the concentration of ions. It also depends on properties of ions, e.g., the ionic radius, which allows for identification of metal ions by analyzing the parameters of the signal: the retention time (RT), half width (HW), amplitude (A) and integral intensity (INT). The advantage of the new device is the instant responsiveness and easy operation, but also the simple construction based on organic (polymer) technology. The system is "open"-when learned and calibrated adequately, other metal ions can be analyzed. The nanodetector can be used in cases where monitoring of the presence and concentration of metal ions is important.
650 7a TEKNIK OCH TEKNOLOGIERx Nanoteknik0 (SwePub)2102 hsv//swe
650 7a ENGINEERING AND TECHNOLOGYx Nano-technology0 (SwePub)2102 hsv//eng
653 a polyaniline
653 a nanostructures
653 a alkanethiols
653 a monolayers
653 a nanodetector
700a Golczak, Sebastianu Adam Mickiewicz Univ, Fac Chem, Lab Mat Physicochem & Nanotechnol, Umultowska 89b, Poznan, Poland. Adam Mickiewicz Univ, Wielkopolska Ctr Adv Technol WCZT, Umultowska 89c, Poznan, Poland.4 aut
700a Langer, Krzysztofu Adam Mickiewicz Univ, Fac Chem, Lab Mat Physicochem & Nanotechnol, Umultowska 89b, Poznan, Poland. Adam Mickiewicz Univ, Wielkopolska Ctr Adv Technol WCZT, Umultowska 89c, Poznan, Poland.4 aut0 (Swepub:kth)u1j1f6u3
700a Langer, Jerzy J.u Adam Mickiewicz Univ, Fac Chem, Lab Mat Physicochem & Nanotechnol, Umultowska 89b, Poznan, Poland. Adam Mickiewicz Univ, Wielkopolska Ctr Adv Technol WCZT, Umultowska 89c, Poznan, Poland.4 aut
710a Adam Mickiewicz Univ, Fac Chem, Lab Mat Physicochem & Nanotechnol, Umultowska 89b, Poznan, Poland. Adam Mickiewicz Univ, Wielkopolska Ctr Adv Technol WCZT, Umultowska 89c, Poznan, Poland.4 org
773t Nanomaterialsd : MDPI AGg 9:2q 9:2x 2079-4991
856u https://doi.org/10.3390/nano9020231y Fulltext
856u https://www.mdpi.com/2079-4991/9/2/231/pdf
8564 8u https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-318666
8564 8u https://doi.org/10.3390/nano9020231

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Langer, Jerzy J.
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TEKNIK OCH TEKNOLOGIER
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och Nanoteknik
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