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Study of Ca doping on A- site on the structural and physical properties of BLTMNZ ceramics

Kumari, Poonam (author)
School of Physics, Shoolini University, Solan, HP, India
Rai, Radheshyam (author)
School of Physics, Shoolini University, Solan, HP, India
Kholkin, Anderi L. (author)
Department of glass and ceramics, Aveiro University, Portugal
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Tiwari, Ashutosh (author)
Linköpings universitet,Biosensorer och bioelektronik,Tekniska högskolan
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 (creator_code:org_t)
2014-05-01
2014
English.
In: Advanced Materials Letters. - : Vinova Bhave Research Institute. - 0976-3961 .- 0976-397X. ; 5:5, s. 255-259
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • The ferroelectric Ca doped (Ba0.9575La0.04X0.0025) (Ti0.815Mn0.0025Nb0.0025Zr0.18)0.99O3 was prepared by a high-temperature solid state reaction technique. For the understanding of the electrical and dielectric property, the relation between the crystal structures, electrical transition and ferroelectric transitions with increasing temperature (–160 to 35°C) have been analyzed. X-ray diffraction analysis of the powders suggests the formation of a single-phase material with monoclinic structure. Capacitance and tanδ of the specimens were measured in the temperature range from -160 to 35°Cat frequencies 1 kHz – 1 MHz. Detailed studies of dielectric and electrical properties indicate that the Curie temperature shifted to higher temperature with the increase in frequency. Moreover, the dielectric maxima dropped down rapidly initially and the dielectric peaks became extremely broad. The AC conductivity increases with increase in frequency. The low value of activation energy obtained for the ceramic samples could be attributed to the influence of electronic contribution to the conductivity.

Subject headings

TEKNIK OCH TEKNOLOGIER  -- Naturresursteknik -- Energisystem (hsv//swe)
ENGINEERING AND TECHNOLOGY  -- Environmental Engineering -- Energy Systems (hsv//eng)

Keyword

Dielectric properties; Perovskite; lead-free ceramics; high dielectrics.

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Kumari, Poonam
Rai, Radheshyam
Kholkin, Anderi ...
Tiwari, Ashutosh
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ENGINEERING AND TECHNOLOGY
ENGINEERING AND ...
and Environmental En ...
and Energy Systems
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Advanced Materia ...
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Linköping University

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