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| Fältnamn | Indikatorer | Metadata |
|---|---|---|
| 000 | 02469naa a2200301 4500 | |
| 001 | oai:DiVA.org:liu-47683 | |
| 003 | SwePub | |
| 008 | 091011s2000 | |||||||||||000 ||eng| | |
| 024 | 7 | a https://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-476832 URI |
| 024 | 7 | a https://doi.org/10.1016/S0013-4686(99)00433-82 DOI |
| 040 | a (SwePub)liu | |
| 041 | a engb eng | |
| 042 | 9 SwePub | |
| 072 | 7 | a ref2 swepub-contenttype |
| 072 | 7 | a art2 swepub-publicationtype |
| 100 | 1 | a Idla, K.u Laboratory of Physical Chemistry, Tallinn Tech. Univ., Ehitajate T., Tallinn, Estonia4 aut |
| 245 | 1 0 | a Good adhesion between chemically oxidized titanium and electrochemically deposited polypyrrole |
| 264 | 1 | c 2000 |
| 338 | a print2 rdacarrier | |
| 520 | a A method for producing extremely adhesive polypyrrole (Ppy) films is described. The electrochemical synthesis of Ppy on thin chemically pre-oxidized Ti layers produces a mechanically strong, shiny polymer film with extremely good adhesion. Adhesion of Ppy films on Ti metal without chemical pre-oxidation is very weak. Two multilayer systems are described with Ppy as an electrochemically active layer, chemically oxidized Ti (TixOy) as a thin adhesive layer, and either a Si-wafer or Al foil as a substrate. Ppy films survive more than 6000 reduction-oxidation cycles in aqueous electrolyte without delamination. The possible mechanisms of enhanced adhesion are discussed. Those are: (1) increased adhesion due to changes in the chemical composition and surface structure of the pre-oxidized Ti, (2) the possibility of the chemical oxidation of pyrrole on the metal surface in addition to the electrochemical polymerization, (3) the adsorption of pyrrole molecules onto pre-oxidized Ti surface by interaction with Ti hydroxides on surface, and (4) the simultaneous growth of TixOy and Ppy. | |
| 653 | a TECHNOLOGY | |
| 653 | a TEKNIKVETENSKAP | |
| 700 | 1 | a Inganäs, Olleu Linköpings universitet,Tekniska högskolan,Biomolekylär och Organisk Elektronik4 aut0 (Swepub:liu)ollin59 |
| 700 | 1 | a Strandberg, M.u Edison Centre, Pikk 39, 10133, Tallinn, Estonia4 aut |
| 710 | 2 | a Laboratory of Physical Chemistry, Tallinn Tech. Univ., Ehitajate T., Tallinn, Estoniab Tekniska högskolan4 org |
| 773 | 0 | t Electrochimica Actag 45:13, s. 2121-2130q 45:13<2121-2130x 0013-4686x 1873-3859 |
| 856 | 4 8 | u https://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-47683 |
| 856 | 4 8 | u https://doi.org/10.1016/S0013-4686(99)00433-8 |
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