Raman spectroscopic studies of the structure of supersaturated ammonium dihydrogen phosphate solutions

Berglund, Kris (author)

(creator_code:org_t)

Amsterdam : Elsevier, 1984
1984
English.
In: Industrial crystallization 84. - Amsterdam : Elsevier. - 0444424067 ; , s. 233-236

Abstract Subject headings

Raman spectroscopic studies of quiescent under and supersaturated ammonium dihydrogen phosphate (ADP) aqueous solutions were performed on the nu //1 (totally symmetric or breathing mode) and nu //3 (symmetric twist) H//2PO//4 OVER BAR bands as well as for the nu //1 band of solid ADP and solid diammonium hydrogen phosphate (DHP). The splitting of the non-degenerate ADP nu //1 band in concentrated solution is interpreted in terms of a well-ordered quasi-crystalline solution structure. Increases in nu //1 half-width at half-height support this view.

About the subject

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