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Thermodynamic mechanism of complex fluids-solids interfacial interaction

Lu, Xiaohua (author)
State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 211800, Jiangsu, China
Dong, Yihui (author)
State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 211800, Jiangsu, China
An, Rong (author)
Herbert Gleiter Institute of Nanoscience, School of Materials Science and Engineering, Nanjing University of Science & Technology, Nanjing 210094, Jiangsu, China
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Wu, Nanhua (author)
Herbert Gleiter Institute of Nanoscience, School of Materials Science and Engineering, Nanjing University of Science & Technology, Nanjing 210094, Jiangsu, China
Ji, Xiaoyan (author)
Luleå tekniska universitet,Energivetenskap
Dai, Zhongyang (author)
State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 211800, Jiangsu, China
Zhu, Yudan (author)
State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 211800, Jiangsu, China
Feng, Xin (author)
State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 211800, Jiangsu, China
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 (creator_code:org_t)
Materials China, 2019
2019
Chinese.
In: Huagong Xuebao/CIESC Journal. - : Materials China. - 0438-1157. ; 70:10, s. 3677-3689
  • Research review (peer-reviewed)
Abstract Subject headings
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  • Interfacial transfer at mesoscale is a common issue for all the multi-phase chemical processes, and the related study remains as a scientific challenge due to the complexities. Investigating the interfacial interactions at mesoscale to find out the regulation strategies is the key to realize process-intensification of mass-transfer and reaction for the advanced chemical industries. To accurately describe the behavior of fluids at the interface, a new molecular thermodynamic model that can describe the complex fluid-solid interface interaction. When the molecular thermodynamic modeling method is extended to the nano-micro interfacial transfer needs to be developed, calling for the coordination of advanced experiments at nano-micro scale and molecular with molocular thermodynamic modelling. Atomic force microscopy (AFM), which possess the sensitivity down to nanoscale, can directly obtain the interfacial interaction at nano-micro scale. The quantification of AFM-measured forces can be used to construct the coarse-grained molecular model and describe complex interfacial interaction. Then, the coarse-grained molecular model can reveal the molecular thermodynamic mechanism of nano- and micro- interface transfer, realizing quantitative prediction.

Subject headings

TEKNIK OCH TEKNOLOGIER  -- Maskinteknik -- Energiteknik (hsv//swe)
ENGINEERING AND TECHNOLOGY  -- Mechanical Engineering -- Energy Engineering (hsv//eng)

Keyword

Energiteknik
Energy Engineering

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