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A 3D extra-large-po...
A 3D extra-large-pore zeolite enabled by 1D-to-3D topotactic condensation of a chain silicate
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- Li, Jian (author)
- Stockholms universitet,Institutionen för material- och miljökemi (MMK),Anhui ZEO New Material Technology Co., China; Peking University, China
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Gao, Zihao Rei (author)
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Lin, Qing-Fang (author)
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Liu, Chenxu (author)
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Gao, Fangxin (author)
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Lin, Cong (author)
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Zhang, Siyao (author)
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Deng, Hua (author)
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Mayoral, Alvaro (author)
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Fan, Wei (author)
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Luo, Song (author)
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Chen, Xiaobo (author)
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He, Hong (author)
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Camblor, Miguel A. (author)
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Chen, Fei-Jian (author)
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Yu, Jihong (author)
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(creator_code:org_t)
- American Association for the Advancement of Science (AAAS), 2023
- 2023
- English.
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In: Science. - : American Association for the Advancement of Science (AAAS). - 0036-8075 .- 1095-9203. ; 379:6629, s. 283-287
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- Zeolites are microporous silicates with a large variety of applications as catalysts, adsorbents, and cation exchangers. Stable silica-based zeolites with increased porosity are in demand to allow adsorption and processing of large molecules but challenge our synthetic ability. We report a new, highly stable pure silica zeolite called ZEO-3, which has a multidimensional, interconnected system of extra-large pores open through windows made by 16 and 14 silicate tetrahedra, the least dense polymorph of silica known so far. This zeolite was formed by an unprecedented one-dimensional to three-dimensional (1D-to-3D) topotactic condensation of a chain silicate. With a specific surface area of more than 1000 square meters per gram, ZEO-3 showed a high performance for volatile organic compound abatement and recovery compared with other zeolites and metal-organic frameworks.
Subject headings
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Publication and Content Type
- ref (subject category)
- art (subject category)
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- By the author/editor
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Li, Jian
-
Gao, Zihao Rei
-
Lin, Qing-Fang
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Liu, Chenxu
-
Gao, Fangxin
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Lin, Cong
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show more...
-
Zhang, Siyao
-
Deng, Hua
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Mayoral, Alvaro
-
Fan, Wei
-
Luo, Song
-
Chen, Xiaobo
-
He, Hong
-
Camblor, Miguel ...
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Chen, Fei-Jian
-
Yu, Jihong
-
show less...
- About the subject
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Chemical Science ...
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Science
- By the university
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Stockholm University