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High-pressure studies of Nano/sub-micrometer C70 rods

Wang, Lin (author)
Liu, Bingbing (author)
Liu, Dedi (author)
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Hou, Yuanyuan (author)
Yao, Mingguang (author)
Zou, Guangtian (author)
Li, H. (author)
Luo, Z.J. (author)
Li, Y.C. (author)
Liu, J. (author)
Sundqvist, Bertil (author)
Umeå universitet,Institutionen för fysik
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 (creator_code:org_t)
2005
2005
English.
In: High Energy Physics and Nuclear Physics B. - 0254-3052. ; 29:Supplement, s. 112-115
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • We have successfully synthesized C-70 rods in nano/sub-micrometers scale by evaporating solvent method. The diameter of the as grown C-70 rods is similar to 500 nm, and the length is similar to 10 mu m. The EDXD pattern and Raman spectroscopy for as -grown sample indicate that the as grown C-70 rod is in hcp structure. The pressure-induced structural phase transition has been studied by using DAC combined with EDXD and Raman spectroscopy methods under quasi-hydrostatic pressure up to 26.1GPa. It is found that hcp structure transforms into amorphous phase for C-70 rods in the pressure range from 23.3 to 26.1GPa, which is higher than the transformation pressure for bulk C-70 crystals. The phase transition is irreversible and it is induced by the collapse of C-70 cage.

Subject headings

NATURVETENSKAP  -- Fysik -- Den kondenserade materiens fysik (hsv//swe)
NATURAL SCIENCES  -- Physical Sciences -- Condensed Matter Physics (hsv//eng)

Keyword

Fullerenes
C70
nanoparticles
Raman spectroscopy
electron diffraction
high pressure
Condensed matter physics
Kondenserade materiens fysik

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