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Partial-ion-yield s...
Partial-ion-yield studies of SOCl 2 following x-ray absorption around the S and Cl K edges
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Bowen, K. P. (author)
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Stolte, W. C. (author)
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Lago, A. F. (author)
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Daacutevalos, J. Z. (author)
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- Piancastelli, M. N. (author)
- Uppsala universitet,Yt- och gränsskiktsvetenskap
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Lindle, D. W. (author)
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(creator_code:org_t)
- AIP Publishing, 2012
- 2012
- English.
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In: Journal of Chemical Physics. - : AIP Publishing. - 0021-9606 .- 1089-7690. ; 137:20, s. 204313-
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- We present a series of photoabsorption and partial-ion-yield experiments on thionyl chloride, SOCl2, at both the sulfur and chlorine K edges. The photoabsorption results exhibit better resolution than previously published data, leading to alternate spectral assignments for some of the features, particularly in the Rydberg-series region. Based on measured fragmentation patterns, we suggest the LUMO, of a' character, is delocalized over the entire molecular skeleton. Unusual behavior of the S2+ fragment hints at a relatively localized bond rupture (the S-O bond below the S K edge and the S-Cl bonds below the Cl K edge) following excitation to some of the higher lying intermediate states.
Subject headings
- NATURVETENSKAP -- Fysik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences (hsv//eng)
Publication and Content Type
- ref (subject category)
- art (subject category)
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