Sökning: onr:"swepub:oai:lup.lub.lu.se:0f0ad058-8f62-4435-9a47-5e9b8c6cae73" > Long-Range Electros...
Fältnamn | Indikatorer | Metadata |
---|---|---|
000 | 03435naa a2200361 4500 | |
001 | oai:lup.lub.lu.se:0f0ad058-8f62-4435-9a47-5e9b8c6cae73 | |
003 | SwePub | |
008 | 211227s2021 | |||||||||||000 ||eng| | |
024 | 7 | a https://lup.lub.lu.se/record/0f0ad058-8f62-4435-9a47-5e9b8c6cae732 URI |
024 | 7 | a https://doi.org/10.1021/jacs.1c047812 DOI |
040 | a (SwePub)lu | |
041 | a engb eng | |
042 | 9 SwePub | |
072 | 7 | a art2 swepub-publicationtype |
072 | 7 | a ref2 swepub-contenttype |
100 | 1 | a Sanchez-Fernandez, Adrianu Lund University,Lunds universitet,Avdelningen för livsmedel och läkemedel,Institutionen för processteknik och tillämpad biovetenskap,Institutioner vid LTH,Lunds Tekniska Högskola,Division of Food and Pharma,Department of Process and Life Science Engineering,Departments at LTH,Faculty of Engineering, LTH4 aut0 (Swepub:lu)ad2225sa |
245 | 1 0 | a Long-Range Electrostatic Colloidal Interactions and Specific Ion Effects in Deep Eutectic Solvents |
264 | c 2021-08-30 | |
264 | 1 | b American Chemical Society (ACS),c 2021 |
300 | a 11 s. | |
520 | a While the traditional consensus dictates that high ion concentrations lead to negligible long-range electrostatic interactions, we demonstrate that electrostatic correlations prevail in deep eutectic solvents where intrinsic ion concentrations often surpass 2.5 M. Here we present an investigation of intermicellar interactions in 1:2 choline chloride:glycerol and 1:2 choline bromide:glycerol using small-angle neutron scattering. Our results show that long-range electrostatic repulsions between charged colloidal particles occur in these solvents. Interestingly, micelle morphology and electrostatic interactions are modulated by specific counterion condensation at the micelle interface despite the exceedingly high concentration of the native halide from the solvent. This modulation follows the trends described by the Hofmeister series for specific ion effects. The results are rationalized in terms of predominant ion-ion correlations, which explain the reduction in the effective ionic strength of the continuum and the observed specific ion effects. | |
650 | 7 | a NATURVETENSKAPx Kemi0 (SwePub)1042 hsv//swe |
650 | 7 | a NATURAL SCIENCESx Chemical Sciences0 (SwePub)1042 hsv//eng |
700 | 1 | a Jackson, Andrew J.u Lund University,Lunds universitet,Fysikalisk kemi,Enheten för fysikalisk och teoretisk kemi,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Physical Chemistry,Physical and theoretical chemistry,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH,European Spallation Source ERIC, Sweden4 aut0 (Swepub:lu)fkem-ajo |
700 | 1 | a Prévost, Sylvain F.u Institut Laue Langevin4 aut |
700 | 1 | a Doutch, James J.u ISIS Neutron and Muon Source4 aut |
700 | 1 | a Edler, Karen J.u University of Bath4 aut0 (Swepub:lu)ka7148ed |
710 | 2 | a Avdelningen för livsmedel och läkemedelb Institutionen för processteknik och tillämpad biovetenskap4 org |
773 | 0 | t Journal of the American Chemical Societyd : American Chemical Society (ACS)g 143:35, s. 14158-14168q 143:35<14158-14168x 0002-7863x 1520-5126 |
856 | 4 | u http://dx.doi.org/10.1021/jacs.1c04781x freey FULLTEXT |
856 | 4 | u https://pubs.acs.org/doi/pdf/10.1021/jacs.1c04781 |
856 | 4 8 | u https://lup.lub.lu.se/record/0f0ad058-8f62-4435-9a47-5e9b8c6cae73 |
856 | 4 8 | u https://doi.org/10.1021/jacs.1c04781 |
Kungliga biblioteket hanterar dina personuppgifter i enlighet med EU:s dataskyddsförordning (2018), GDPR. Läs mer om hur det funkar här.
Så här hanterar KB dina uppgifter vid användning av denna tjänst.
Kopiera och spara länken för att återkomma till aktuell vy