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Sökning: onr:"swepub:oai:lup.lub.lu.se:c6d880fd-9303-4f31-9264-f6674337eb7c" > Overcoming small-ba...

LIBRIS Formathandbok  (Information om MARC21)
FältnamnIndikatorerMetadata
00004218naa a2200517 4500
001oai:lup.lub.lu.se:c6d880fd-9303-4f31-9264-f6674337eb7c
003SwePub
008240216s2024 | |||||||||||000 ||eng|
024a https://lup.lub.lu.se/record/c6d880fd-9303-4f31-9264-f6674337eb7c2 URI
024a https://doi.org/10.1038/s41467-024-45085-62 DOI
040 a (SwePub)lu
041 a engb eng
042 9 SwePub
072 7a art2 swepub-publicationtype
072 7a ref2 swepub-contenttype
100a Elsayed, Mohamed Hammadu National Tsing Hua University,National Taiwan University4 aut
2451 0a Overcoming small-bandgap charge recombination in visible and NIR-light-driven hydrogen evolution by engineering the polymer photocatalyst structure
264 1c 2024
520 a Designing an organic polymer photocatalyst for efficient hydrogen evolution with visible and near-infrared (NIR) light activity is still a major challenge. Unlike the common behavior of gradually increasing the charge recombination while shrinking the bandgap, we present here a series of polymer nanoparticles (Pdots) based on ITIC and BTIC units with different π-linkers between the acceptor-donor-acceptor (A-D-A) repeated moieties of the polymer. These polymers act as an efficient single polymer photocatalyst for H2 evolution under both visible and NIR light, without combining or hybridizing with other materials. Importantly, the difluorothiophene (ThF) π-linker facilitates the charge transfer between acceptors of different repeated moieties (A-D-A-(π-Linker)-A-D-A), leading to the enhancement of charge separation between D and A. As a result, the PITIC-ThF Pdots exhibit superior hydrogen evolution rates of 279 µmol/h and 20.5 µmol/h with visible (>420 nm) and NIR (>780 nm) light irradiation, respectively. Furthermore, PITIC-ThF Pdots exhibit a promising apparent quantum yield (AQY) at 700 nm (4.76%).
650 7a NATURVETENSKAPx Kemix Polymerkemi0 (SwePub)104062 hsv//swe
650 7a NATURAL SCIENCESx Chemical Sciencesx Polymer Chemistry0 (SwePub)104062 hsv//eng
650 7a NATURVETENSKAPx Kemix Fysikalisk kemi0 (SwePub)104022 hsv//swe
650 7a NATURAL SCIENCESx Chemical Sciencesx Physical Chemistry0 (SwePub)104022 hsv//eng
700a Abdellah, Mohamedu Lund University,Lunds universitet,Kemisk fysik,Enheten för fysikalisk och teoretisk kemi,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,LU profilområde: Ljus och material,Lunds universitets profilområden,Chemical Physics,Physical and theoretical chemistry,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH,LU Profile Area: Light and Materials,Lund University Profile areas,United Arab Emirates University,South Valley University4 aut0 (Swepub:lu)mo5485ab
700a Alhakemy, Ahmed Zaki4 aut
700a Mekhemer, Islam M.A.u National Tsing Hua University4 aut
700a Aboubakr, Ahmed Esmail A.4 aut
700a Chen, Bo Hanu National Tsing Hua University4 aut
700a Sabbah, Amru National Taiwan University4 aut
700a Lin, Kun Hanu National Tsing Hua University4 aut
700a Chiu, Wen Shengu National Chung-Hsing University4 aut
700a Lin, Sheng Jieu National Chung-Hsing University4 aut
700a Chu, Che Yiu National Chung-Hsing University4 aut
700a Lu, Chih Hsuanu National Tsing Hua University4 aut
700a Yang, Shang Dau National Tsing Hua University4 aut
700a Mohamed, Mohamed Gamalu National Sun Yat-sen University4 aut
700a Kuo, Shiao Weiu National Sun Yat-sen University4 aut
700a Hung, Chen Hsiung4 aut
700a Chen, Li Chyongu National Taiwan University4 aut
700a Chen, Kuei Hsienu National Taiwan University4 aut
700a Chou, Ho Hsiuu National Tsing Hua University4 aut
710a National Tsing Hua Universityb National Taiwan University4 org
773t Nature Communicationsg 15:1q 15:1x 2041-1723
856u http://dx.doi.org/10.1038/s41467-024-45085-6x freey FULLTEXT
8564 8u https://lup.lub.lu.se/record/c6d880fd-9303-4f31-9264-f6674337eb7c
8564 8u https://doi.org/10.1038/s41467-024-45085-6

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