Search: onr:"swepub:oai:research.chalmers.se:d879f0c6-48b3-429b-9dfa-7a891c6a78bc" >
Tailoring Phase Pur...
Tailoring Phase Purity in the 2D/3D Perovskite Heterostructures Using Lattice Mismatch
-
- Xiong, Min (author)
- Nanchang Univ, Peoples R China
-
- Zou, Wenjun (author)
- Nanchang Univ, Peoples R China
-
- Fan, Ke (author)
- Hong Kong Polytech Univ, Peoples R China
-
show more...
-
- Qin, Chaochao (author)
- Henan Normal Univ, Peoples R China
-
- Li, Sibo (author)
- Nanchang Univ, Peoples R China
-
- Fei, Linfeng (author)
- Nanchang Univ, Peoples R China
-
- Jiang, Jizhong (author)
- Jilin Univ, Peoples R China
-
- Huang, Haitao (author)
- Hong Kong Polytech Univ, Peoples R China
-
- Shen, Liang (author)
- Jilin Univ, Peoples R China
-
- Gao, Feng, 1981- (author)
- Linköpings universitet,Elektroniska och fotoniska material,Tekniska fakulteten
-
- Jen, Alex K-Y (author)
- City Univ Hong Kong, Peoples R China
-
- Yao, Kai (author)
- Nanchang Univ, Peoples R China
-
show less...
-
(creator_code:org_t)
- 2022-01-04
- 2022
- English.
-
In: ACS Energy Letters. - : AMER CHEMICAL SOC. - 2380-8195. ; 7:1, s. 550-559
- Related links:
-
https://urn.kb.se/re...
-
show more...
-
https://doi.org/10.1...
-
show less...
Abstract
Subject headings
Close
- Although the fabrication of two-dimensional (2D)/three-dimensional (3D) halide perovskite heterostructures has been employed to balance the long-term stability and high efficiency of perovskite solar cells, the formation of metastable quasi-2D perovskites remains the most serious challenge. Here, we demonstrate that large lattice mismatch derived from halide and cation differences between 2D and 3D perovskites are key to avoiding the formation of unintended 2D phases in the preparation of 2D/3D bulk heterostructure because the phase transformation becomes less thermodynamically favorable. Specifically, by employing chloride 2D perovskite (PYA)(2) PbCl4 (PYA = propargylammonium) crystals into a 3D precursor solution, we achieve a phase-pure 2D/3D heterojunction with clean type-I band alignment, which exhibits greatly reduced charge recombination. Furthermore, the incorporation of alkyne perovskites is also shown to suppress iodine diffusion and formation due to their exceptional iodine capture capacity. The resultant 2D/3D heterostructured devices exhibited enhanced efficiencies and stabilities compared with their 3D counterparts.
Subject headings
- NATURVETENSKAP -- Kemi -- Materialkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Materials Chemistry (hsv//eng)
Publication and Content Type
- ref (subject category)
- art (subject category)
Find in a library
To the university's database
- By the author/editor
-
Xiong, Min
-
Zou, Wenjun
-
Fan, Ke
-
Qin, Chaochao
-
Li, Sibo
-
Fei, Linfeng
-
show more...
-
Jiang, Jizhong
-
Huang, Haitao
-
Shen, Liang
-
Gao, Feng, 1981-
-
Jen, Alex K-Y
-
Yao, Kai
-
show less...
- About the subject
-
- NATURAL SCIENCES
-
NATURAL SCIENCES
-
and Chemical Science ...
-
and Materials Chemis ...
- Articles in the publication
-
ACS Energy Lette ...
- By the university
-
Linköping University