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Exploring Supramole...
Exploring Supramolecular Gels in Flow-Type Chemistry-Design and Preparation of Stationary Phases
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- Zacharias, Savannah C. (author)
- Gothenburg University,Göteborgs universitet,Institutionen för kemi och molekylärbiologi,Department of Chemistry and Molecular Biology,University of Gothenburg
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- Kamlar, Martin, 1981 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Sundén, Henrik, 1978 (author)
- Gothenburg University,Göteborgs universitet,Institutionen för kemi och molekylärbiologi,Department of Chemistry and Molecular Biology,Chalmers tekniska högskola,Chalmers University of Technology,University of Gothenburg
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(creator_code:org_t)
- 2021-07-09
- 2021
- English.
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In: Industrial & Engineering Chemistry Research. - : American Chemical Society (ACS). - 0888-5885 .- 1520-5045. ; 60:28, s. 10056-10063
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Abstract
Subject headings
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- Two major challenges facing chemical synthesis are product isolation and catalyst recovery. One method to overcome these challenges is to perform the synthesis in a flow system with a catalytic stationary phase. However, the polymeric catalytic materials used in flow systems are often laborious to produce. In this study, we investigate a novel supramolecular gel as a catalytic stationary phase material. The gel is based on a modular, easy to synthesize, oxotriphenylhexanoate (OTHO) gelator comprised of a catalytic unit designed to catalyze the Knoevenagel reaction. The catalytic organogel enhances the rate of product formation and can be reused five times. Use of the OTHO to construct catalytic gels is a flexible technique that can be utilized to improve product isolation and reduce wastage of the catalyst.
Subject headings
- TEKNIK OCH TEKNOLOGIER -- Kemiteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Chemical Engineering (hsv//eng)
- TEKNIK OCH TEKNOLOGIER -- Kemiteknik -- Kemiska processer (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Chemical Engineering -- Chemical Process Engineering (hsv//eng)
- TEKNIK OCH TEKNOLOGIER -- Kemiteknik -- Annan kemiteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Chemical Engineering -- Other Chemical Engineering (hsv//eng)
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
Keyword
- organic-synthesis
- ionic liquids
- light
- rheology
- catalyst
- gelation
- Engineering
Publication and Content Type
- ref (subject category)
- art (subject category)
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