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Synthesis of Novel Aryl and Heteroaryl Acyl Sulfonimidamides via Pd-Catalyzed Carbonylation Using a Nongaseous Precursor
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- Borhade, Sanjay R. (author)
- Uppsala universitet,Avdelningen för organisk farmaceutisk kemi
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- Sandström, Anja (author)
- Uppsala universitet,Avdelningen för organisk farmaceutisk kemi
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- Arvidsson, Per I. (author)
- Uppsala universitet,Avdelningen för organisk farmaceutisk kemi
- (creator_code:org_t)
- 2013-02-08
- 2013
- English.
- In: Organic Letters. - : American Chemical Society (ACS). - 1523-7060 .- 1523-7052. ; 15:5, s. 1056-1059
- Journal article (peer-reviewed)
Abstract
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- Hitherto unexplored aryl and heteroaryl acyl sulfonimidamides have been prepared through the development of a new Pd-catalyzed carbonylation protocol. This novel methodology, employing sulfonimidamides as nucleophiles and CO gas ex situ released from solid Mo(CO)(6) in a sealed two-chamber system, yields a wide range of carbamate protected acyl sulfonimidamides in good to excellent yields.
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