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LIBRIS Formathandbok  (Information om MARC21)
FältnamnIndikatorerMetadata
00003726naa a2200445 4500
001oai:research.chalmers.se:fa023a8a-a5f2-4cc4-af66-c43f3af96272
003SwePub
008171008s2013 | |||||||||||000 ||eng|
0247 a https://doi.org/10.1038/ncomms31212 DOI
0247 a https://research.chalmers.se/publication/1804262 URI
040 a (SwePub)cth
041 a engb eng
042 9 SwePub
072 7a art2 swepub-publicationtype
072 7a ref2 swepub-contenttype
1001 a Hao, Xianu Danmarks Tekniske Universitet,Technical University of Denmark,Chinese Academy of Sciences4 aut
2451 0a Direct measurement and modulation of single-molecule coordinative bonding forces in a transition metal complex
264 c 2013-07-02
264 1b Springer Science and Business Media LLC,c 2013
520 a Coordination chemistry has been a consistently active branch of chemistry since Werner’s seminal theory of coordination compounds inaugurated in 1893, with the central focus on transition metal complexes. However, control and measurement of metal–ligand interactions at the single-molecule level remain a daunting challenge. Here we demonstrate an interdisciplinary and systematic approach that enables measurement and modulation of the coordinative bonding forces in a transition metal complex. Terpyridine is derived with a thiol linker, facilitating covalent attachment of this ligand on both gold substrate surfaces and gold-coated atomic force microscopy tips. The coordination and bond breaking between terpyridine and osmium are followed in situ by electrochemically controlled atomic force microscopy at the single-molecule level. The redox state of the central metal atom is found to have a significant impact on the metal–ligand interactions. The present approach represents a major advancement in unravelling the nature of metal–ligand interactions and could have broad implications in coordination chemistry.
650 7a NATURVETENSKAPx Kemix Oorganisk kemi0 (SwePub)104042 hsv//swe
650 7a NATURAL SCIENCESx Chemical Sciencesx Inorganic Chemistry0 (SwePub)104042 hsv//eng
650 7a TEKNIK OCH TEKNOLOGIERx Nanoteknik0 (SwePub)2102 hsv//swe
650 7a ENGINEERING AND TECHNOLOGYx Nano-technology0 (SwePub)2102 hsv//eng
7001 a Zhu, Nanu Danmarks Tekniske Universitet,Technical University of Denmark4 aut
7001 a Gschneidtner, Tina,d 1985u Chalmers tekniska högskola,Chalmers University of Technology4 aut0 (Swepub:cth)tinag
7001 a Jönsson, Elvar Ö.u Danmarks Tekniske Universitet,Technical University of Denmark4 aut
7001 a Zhang, Jingdongu Danmarks Tekniske Universitet,Technical University of Denmark4 aut
7001 a Moth-Poulsen, Kasper,d 1978u Chalmers tekniska högskola,Chalmers University of Technology4 aut0 (Swepub:cth)mkasper
7001 a Wang, Hongdau Chinese Academy of Sciences4 aut
7001 a Thygesen, Kristian S.u Danmarks Tekniske Universitet,Technical University of Denmark4 aut
7001 a Jacobsen, K. W.u Danmarks Tekniske Universitet,Technical University of Denmark4 aut
7001 a Ulstrup, Jensu Danmarks Tekniske Universitet,Technical University of Denmark4 aut
7001 a Chi, Qijinu Danmarks Tekniske Universitet,Technical University of Denmark4 aut
7102 a Danmarks Tekniske Universitetb Chinese Academy of Sciences4 org
7730 t Nature Communicationsd : Springer Science and Business Media LLCg 4q 4x 2041-1723x 2041-1723
8564 u http://dx.doi.org/10.1038/ncomms3121y FULLTEXT
8564 u https://www.nature.com/articles/ncomms3121.pdf
8564 8u https://doi.org/10.1038/ncomms3121
8564 8u https://research.chalmers.se/publication/180426

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