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Search: WFRF:(Gong P.) > (1998-1999) > Biodegradability of...

LIBRIS Formathandbok  (Information om MARC21)
FältnamnIndikatorerMetadata
00004021naa a2200361 4500
001oai:DiVA.org:kth-166036
003SwePub
008150430s1999 | |||||||||||000 ||eng|
024a https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-1660362 URI
024a https://doi.org/10.1021/ie99008692 DOI
040 a (SwePub)kth
041 a engb eng
042 9 SwePub
072 7a ref2 swepub-contenttype
072 7a art2 swepub-publicationtype
100a Zhang, L4 aut
2451 0a Biodegradability of regenerated cellulose films coated with polyurethane/natural polymers interpenetrating polymer networks
264 c 1999-09-18
264 1b American Chemical Society (ACS),c 1999
338 a print2 rdacarrier
500 a QC 20150507
520 a Interpenetrating polymer network (IPN) coatings synthesized from castor- oil-based polyurethane (PU) with chitosan, nitrocellulose, or elaeostearin were coated on regenerated cellulose (RC) film for curing at 80-100 °C for 2-5 min, providing biodegradable, water-resistant cellulose films coded, respectively, as RCCH, RCNC, and RCEs. The coated films were buried in natural soil for decaying and inoculated with a spore suspension of fungi on the agar medium, respectively, to test biodegradability. The viscosity- average molecular weight, M(n), and the weight of the degraded films decreased sharply with the progress of degradation. The degradation half- lifes, t(1/2), of the films in soil at 30 °C were found to be 19 days for RC, 25 days for RCNC, 32 days for RCCH, and 45 days for the RCEs films. Scanning electron microscopy (SEM) showed that the extent of decay followed in the order RC > RCNC > RCCH > RCEs. SEM, infrared (IR), high-performance liquid chromatography (HPLC), and CO2 evolution results indicated that the microorganisms directly attacked the water-resistant coating layer and then penetrated into the cellulose to speedily metabolize, while accompanying with producing CO2, H2O, glucose cleaved from cellulose, and small molecules decomposed from the coatings.Interpenetrating polymer network (IPN) coatings synthesized from castor-oil-based polyurethane (PU) with chitosan, nitrocellulose, or elaeostearin were coated on regenerated cellulose (RC) film for curing at 80-100°C for 2-5 min, providing biodegradable, water-resistant cellulose films coded, respectively, as RCCH, RCNC, and RCEs. The coated films were buried in natural soil for decaying and inoculated with a spore suspension of fungi on the agar medium, respectively, to test biodegradability. The viscosity-average molecular weight, Mη, and the weight of the degraded films decreased sharply with the process of degradation. The degradation half-lifes, t1/2, of the films in soil at 30°C were found to be 19 days for RC, 25 days for RCNC, 32 days for RCCH, and 45 days for the RCEs films. Scanning electron microscopy (SEM) showed that the extent of decay followed in the order RC > RCNC > RCCH > RCEs. SEM, infrared (IR), high-performance liquid chromatography (HPLC), and CO2 evolution results indicated that the microorganisms directly attacked the water-resistant coating layer and then penetrated into the cellulose to speedily metabolize, while accompanying with producing CO2, H2O, glucose cleaved from cellulose, and small molecules decomposed from the coatings.
650 7a TEKNIK OCH TEKNOLOGIERx Materialteknikx Pappers-, massa- och fiberteknik0 (SwePub)205032 hsv//swe
650 7a ENGINEERING AND TECHNOLOGYx Materials Engineeringx Paper, Pulp and Fiber Technology0 (SwePub)205032 hsv//eng
700a Zhou, JP4 aut
700a Huang, J4 aut
700a Gong, P4 aut
700a Zhou, Q4 aut
700a Zheng, LS4 aut
700a Du, YM4 aut
773t Industrial & Engineering Chemistry Researchd : American Chemical Society (ACS)g 38:11, s. 4284-4289q 38:11<4284-4289x 0888-5885x 1520-5045
8564 8u https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-166036
8564 8u https://doi.org/10.1021/ie9900869

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Zhang, L
Zhou, JP
Huang, J
Gong, P
Zhou, Q
Zheng, LS
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Du, YM
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ENGINEERING AND TECHNOLOGY
ENGINEERING AND ...
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Industrial & Eng ...
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Royal Institute of Technology

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