Core-hole localization and ultra-fast dissociation in SF6

Search: WFRF:(Luning S.) > Core-hole localizat...

Ekholm, V. (author): Uppsala University,Lund University,Lunds universitet,MAX IV-laboratoriet,MAX IV Laboratory

Chiuzbaian, G. S. (author): Sorbonne Univ, F-75005 Paris, France.;CNRS, LCPMR, F-75005 Paris, France.;Synchrotron SOLEIL, LOrme Merisiers, BP 48, F-91192 Gif Sur Yvette, France.,Lund Univ, MAX IV Lab, Box 118, SE-22100 Lund, Sweden.,Paris-Sorbonne University

S the, C. (author): Lund University,Lunds universitet,MAX IV-laboratoriet,MAX IV Laboratory

Nicolaou, A. (author): Synchrotron SOLEIL, LOrme Merisiers, BP 48, F-91192 Gif Sur Yvette, France.

Guarise, M. (author): Sorbonne Univ, F-75005 Paris, France.;CNRS, LCPMR, F-75005 Paris, France.;Ctr Nacl Pesquisa Energia & Mat CNPEM, BR-10000 Campinas, Brazil.,Brazilian Center For Research In Energy And Materials (CNPEM),Paris-Sorbonne University

Simon, M. (author): Sorbonne Univ, F-75005 Paris, France.;CNRS, LCPMR, F-75005 Paris, France.,Paris-Sorbonne University

Jaouen, N. (author): Synchrotron SOLEIL, LOrme Merisiers, BP 48, F-91192 Gif Sur Yvette, France.

Luning, J. (author): Sorbonne Univ, F-75005 Paris, France.;CNRS, LCPMR, F-75005 Paris, France.,Paris-Sorbonne University

Hague, C. F. (author): Sorbonne Univ, F-75005 Paris, France.;CNRS, LCPMR, F-75005 Paris, France.,Paris-Sorbonne University

Gel'mukhanov, Faris (author): KTH Royal Institute of Technology,KTH,Teoretisk kemi och biologi,Royal Inst Technol, Sch Biotechnol, Theoret Chem & Biol, S-10691 Stockholm, Sweden.;Siberian Fed Univ, Krasnoyarsk 660041, Russia.;Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.,Siberian Federal University,Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences

Odelius, Michael (author): Stockholm University,Stockholms universitet,Fysikum,Stockholm Univ, AlbaNova Univ Ctr, Dept Phys, SE-10691 Stockholm, Sweden.

Björneholm, Olle (author): Uppsala University,Uppsala universitet,Molekyl- och kondenserade materiens fysik

Rubensson, Jan-Erik (author): Uppsala University,Uppsala universitet,Institutionen för fysik och astronomi

(creator_code:org_t)

2020-07-24
2020
English.
In: Journal of Physics B. - : IOP Publishing. - 0953-4075 .- 1361-6455. ; 53:18

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Abstract Subject headings

Resonant inelastic x-ray scattering spectra excited at the fluorine K resonances of SF(6)have been recorded. While a small but significant propensity for electronically parity-allowed transitions is found, the observation of parity-forbidden electronic transitions is attributed to vibronic coupling that breaks the global inversion symmetry of the electronic wavefunction and localizes the core hole. The dependence of the scattering cross section on the polarization of the incident radiation and the scattering angle is interpreted in terms of local pi/sigma symmetry around the S-F bond. This symmetry selectivity prevails during the dissociation that occurs during the scattering process.

NATURVETENSKAP -- Fysik (hsv//swe)
NATURAL SCIENCES -- Physical Sciences (hsv//eng)
NATURVETENSKAP -- Fysik -- Atom- och molekylfysik och optik (hsv//swe)
NATURAL SCIENCES -- Physical Sciences -- Atom and Molecular Physics and Optics (hsv//eng)

By the author/editor: Ekholm, V.; Chiuzbaian, G. S ...; S the, C.; Nicolaou, A.; Guarise, M.; Simon, M.; show more...; Jaouen, N.; Luning, J.; Hague, C. F.; Gel'mukhanov, Fa ...; Odelius, Michael; Björneholm, Olle; Rubensson, Jan-E ...; show less...

About the subject

NATURAL SCIENCES: NATURAL SCIENCES; and Physical Science ...; and Atom and Molecul ...

By the university: Royal Institute of Technology; Stockholm University; Uppsala University; Lund University

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