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Sökning: WFRF:(Hvitt Strömvall Ann Margret 1963) > Leaching of concret...

LIBRIS Formathandbok  (Information om MARC21)
FältnamnIndikatorerMetadata
00004233naa a2200289 4500
001oai:research.chalmers.se:7078ff21-7c7c-4b38-9cf6-6abcfc398cdd
003SwePub
008171007s2001 | |||||||||||000 ||eng|
024a https://doi.org/10.1021/es000138h2 DOI
024a https://research.chalmers.se/publication/2140642 URI
040 a (SwePub)cth
041 a engb eng
042 9 SwePub
072 7a art2 swepub-publicationtype
072 7a ref2 swepub-contenttype
100a Andersson, Åse,d 1971u Chalmers tekniska högskola,Chalmers University of Technology4 aut
2451 0a Leaching of concrete admixtures containing thiocyanate and resin acids
264 c 2001-01-12
264 1b American Chemical Society (ACS),c 2001
520 a There is an increasing concern about the emission of pollutants during the construction and lifetime of buildings. The leaching of concrete admixtures containing thiocyanate and resin acids was studied using standard leaching tests and chemical analysis. Ecotoxicological risk was assessed for each admixture. Thiocyanate leaching from concrete, with a chlorine-free accelerating admixture, was determined by ion chromatography. Of the total amount of thiocyanate added, 6-8% was emitted within 30 d. The thiocyanate diffusion curve indicates a fast dissolution process from the surface layer, followed by a slower continuous diffusion process. Thiocyanate exhibits both acute and chronic toxicity, which makes it of immediate environmental concern. Resin acid leaching from concrete test specimens containing an admixture of air-entraining agents with tall oil was determined by solid-phase extraction, methylation, and GC/MS. Of added resin acids, 10% was emitted over 143 d. The leaching curves for the resin acids indicate a continuous diffusion that is proportional to the square root of time and follows Fick's first law of diffusion. The chemical composition of the resin acids in the leachate demonstrates degradation and rearrangement of the resin acids during diffusion. Resin acids emitted from concrete are of environmental concern because they are persistent and have the ability to bioaccumulate in aquatic organisms. | There is an increasing concern about the emission of pollutants during the construction and lifetime of buildings. The leaching of concrete admixtures containing thiocyanate and resin acids was studied using standard leaching tests and chemical analysis. Ecotoxicological risk was assessed for each admixture. Thiocyanate leaching from concrete, with a chlorine-free accelerating admixture, was determined by ion chromatography. Of the total amount of thiocyanate added, 6-8% was emitted within 30 d. The thiocyanate diffusion curve indicates a fast dissolution process from the surface layer, followed by a slower continuous diffusion process. Thiocyanate exhibits both acute and chronic toxicity, which makes it of immediate environmental concern. Resin acid leaching from concrete test specimens containing an admixture of air-entraining agents with tall oil was determined by solid-phase extraction, methylation, and GC/MS. Of added resin acids, 10% was emitted over 143 d. The leaching curves for the resin acids indicate a continuous diffusion that is proportional to the square root of time and follows Fick's first law of diffusion. The chemical composition of the resin acids in the leachate demonstrates degradation and rearrangement of the resin acids during diffusion. Resin acids emitted from concrete are of environmental concern because they are persistent and have the ability to bioaccumulate in aquatic organisms.
650 7a TEKNIK OCH TEKNOLOGIERx Samhällsbyggnadsteknik0 (SwePub)2012 hsv//swe
650 7a ENGINEERING AND TECHNOLOGYx Civil Engineering0 (SwePub)2012 hsv//eng
700a Hvitt Strömvall, Ann-Margret,d 1963u Chalmers tekniska högskola,Chalmers University of Technology4 aut0 (Swepub:cth)annmargr
710a Chalmers tekniska högskola4 org
773t Environmental Science & Technologyd : American Chemical Society (ACS)g 35:4, s. 788-793q 35:4<788-793x 0013-936Xx 1520-5851
8564 8u https://doi.org/10.1021/es000138h
8564 8u https://research.chalmers.se/publication/214064

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