Ionic liquid and hybrid ionic liquid/organic electrolytes for high temperature lithium-ion battery application

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Fältnamn	Indikatorer	Metadata
000		03086naa a2200385 4500
001		oai:research.chalmers.se:c0dbc7c5-d579-471c-b60b-edccd2202373
003		SwePub
008		171008s2016 \| \|\|\|\|\|\|\|\|\|\|\|000 \|\|eng\|
024	7	a https://research.chalmers.se/publication/2452612 URI
024	7	a https://doi.org/10.1016/j.electacta.2016.08.0252 DOI
040		a (SwePub)cth
041		a engb eng
042		9 SwePub
072	7	a art2 swepub-publicationtype
072	7	a ref2 swepub-contenttype
100	1	a Plylahan, Nareerat,d 1984u Chalmers tekniska högskola,Chalmers University of Technology4 aut0 (Swepub:cth)nareerat
245	1 0	a Ionic liquid and hybrid ionic liquid/organic electrolytes for high temperature lithium-ion battery application
264	1	b Elsevier BV,c 2016
520		a Ionic liquid (IL) and hybrid IL/organic electrolytes with pyrrolidinium cation based ILs have been investigated for application in high temperature lithium-ion batteries (HT-LIBs). The IL based electrolytes show high thermal stabilities, up to 340 degrees C, ionic conductivities of > 5 x 10(-3) S cm(-1) at 80 degrees C, and broad electrochemical stability windows: 0-5 V vs. Li+/Li degrees. The performance of LiFePO4 based half-cells at 80 degrees C is promising, delivering ca. 160 mAh g(-1) at 1C, with a rate capability up to 4C and ca. 98% coulombic efficiency. The creation of hybrid IL/organic electrolytes by adding different organic cyclic carbonate solvents reduces viscosity of the electrolytes by 28% at 80 degrees C, thereby improving the ion transport, and further improves the electrochemical performance; higher stability, better rate capability, and >= 99% coulombic efficiency. Overall, the electrolytes proposed have a potential to be applied in HT-LIBs, a concept with large advantages at the vehicle system level. (C) 2016 Elsevier Ltd. All rights reserved.
650	7	a NATURVETENSKAPx Fysikx Atom- och molekylfysik och optik0 (SwePub)103022 hsv//swe
650	7	a NATURAL SCIENCESx Physical Sciencesx Atom and Molecular Physics and Optics0 (SwePub)103022 hsv//eng
653		a ionic liquid
653		a high temperature
653		a pyrrolidinium
653		a Lithium-ion battery
653		a organic solvents
700	1	a Kerner, Manfred,d 1984u Chalmers tekniska högskola,Chalmers University of Technology4 aut0 (Swepub:cth)kerner
700	1	a Lim, Du Hyun,d 1983u Chalmers tekniska högskola,Chalmers University of Technology4 aut0 (Swepub:cth)duhyun
700	1	a Matic, Aleksandar,d 1968u Chalmers tekniska högskola,Chalmers University of Technology4 aut0 (Swepub:cth)matic
700	1	a Johansson, Patrik,d 1969u Chalmers tekniska högskola,Chalmers University of Technology4 aut0 (Swepub:cth)jpatrik
710	2	a Chalmers tekniska högskola4 org
773	0	t Electrochimica Actad : Elsevier BVg 216, s. 24-34q 216<24-34x 0013-4686
856	4	u http://dx.doi.org/10.1016/j.electacta.2016.08.025y FULLTEXT
856	4 8	u https://research.chalmers.se/publication/245261
856	4 8	u https://doi.org/10.1016/j.electacta.2016.08.025

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