A Model for Mass Transport of Molten Alkali Carbonate Mixtures Applied to the MCFC

(creator_code:org_t)

The Electrochemical Society, 2006
2006
English.
In: Journal of the Electrochemical Society. - : The Electrochemical Society. - 0013-4651 .- 1945-7111. ; 153:11, s. A2111-A2119

Related links:: http://ecsdl.org/vse...; show more...; https://urn.kb.se/re...; https://doi.org/10.1...; show less...

Abstract Subject headings

A one-dimensional model based on the Stefan-Maxwell formulation for mass transfer of the main components of a binary molten carbonate electrolyte, including all of the nonidealities, was formulated and applied to the molten carbonate fuel cell (MCFC). The Stefan-Maxwell diffusion coefficients were determined from literature transport data; still, a narrow parameter window in electrolyte composition and temperature had to be used to keep the integrity of the fits. The model for calculation of the electrolyte composition was combined with equations describing the current distribution in the electrodes and the electrolyte. The calculated results of the electrolyte composition changes show that they depend predominantly on the current density and the total electrolyte filling degree. It was also concluded that the electrolyte composition changes are less then two percent for Li/K and five percent for Li/Na. This model demonstrates how experimental data measured at equilibrium conditions may be used to determine Stefan-Maxwell diffusion coefficients and then applied to a transport model for the electrolyte, in this case an MCFC.

About the subject

Kungliga biblioteket hanterar dina personuppgifter i enlighet med EU:s dataskyddsförordning (2018), GDPR. Läs mer om hur det funkar här.
Så här hanterar KB dina uppgifter vid användning av denna tjänst.