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Synthesis and Rietveld refinements of new ceramics Sr2CaFe2WO9 and Sr2PbFe2TeO9 perovskites

El Hachmi, Abdelhadi (author)
Univ Hassan Ier, LS3M, Khouribga 25000, Morocco
Tamraoui, Y. (author)
Univ Mohammed VI Polytech, Mat Sci & Nanoengn MSN, Lot 660 Hay Moulay Rachid, Ben Guerir 43150, Morocco;Univ Hassan Ier, LS3M, Khouribga 25000, Morocco
Manoun, Bouchaib (author)
Univ Mohammed VI Polytech, Mat Sci & Nanoengn MSN, Lot 660 Hay Moulay Rachid, Ben Guerir 43150, Morocco;Univ Hassan Ier, LS3M, Khouribga 25000, Morocco
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Haloui, R. (author)
Univ Hassan Ier, LS3M, Khouribga 25000, Morocco
Elaamrani, M. A. (author)
Univ Hassan Ier, LS3M, Khouribga 25000, Morocco
Saadoune, I. (author)
Univ Mohammed VI Polytech, Mat Sci & Nanoengn MSN, Lot 660 Hay Moulay Rachid, Ben Guerir 43150, Morocco;Univ Cadi Ayyad, FST Marrakech, LCME, Av A Khattabi, Marrakech 40000, Morocco
Bih, L. (author)
Univ Moulay Ismail, Fac Sci Meknes, Equipe Phys Chim Matiere Condensee, PCMC, Meknes, Morocco
Lazor, Peter (author)
Uppsala universitet,Mineralogi, petrologi och tektonik
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 (creator_code:org_t)
J C P D S-INT CENTRE DIFFRACTION DATA, 2018
2018
English.
In: Powder Diffraction. - : J C P D S-INT CENTRE DIFFRACTION DATA. - 0885-7156 .- 1945-7413. ; 33:2, s. 134-140
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • Ceramics of Sr2CaFe2WO9 and Sr2PbFe2TeO9 double perovskites have been prepared in polycrystalline form by solid-state technique, in the air. The crystalline structure was analyzed using X-ray powder diffraction (XRPD) at room temperature. Rietveld analysis of XRPD) patterns show that both compounds adopt a tetragonal structure with space group I4/m, with unit cell parameters a = 5.5453(1) angstrom, c = 7.8389(1) angstrom for Sr(2)CaFc(2)WO(9), and a = 5.5994(15) angstrom, c = 7.8979(30) angstrom for Sr2PbFe2TeO9. A certain degree of anti-site disordering of W and/or Te and Fe on the B -sites have been detected, indicating the presence of a partial amount of W and/or Te at Fe positions and vice versa.

Subject headings

NATURVETENSKAP  -- Kemi -- Oorganisk kemi (hsv//swe)
NATURAL SCIENCES  -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)

Keyword

Sr2CaFe2WO9
Sr2PbFe2TeO9 crystal structure
X-ray diffraction

Publication and Content Type

ref (subject category)
art (subject category)

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