A monocarboxylate-bridged diiron(III) mu-oxido complex that catalyzes alkane oxidation by hydrogen peroxide

Jarenmark, Martin (author): Lund University,Lunds universitet,Kemisk fysik,Enheten för fysikalisk och teoretisk kemi,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Chemical Physics,Physical and theoretical chemistry,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH

Turitsyna, Elena A. (author)

Haukka, Matti (author)

Shteinman, Albert A. (author)

Nordlander, Ebbe (author): Lund University,Lunds universitet,Kemisk fysik,Enheten för fysikalisk och teoretisk kemi,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Chemical Physics,Physical and theoretical chemistry,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH

(creator_code:org_t)

Royal Society of Chemistry (RSC), 2010
2010
English.
In: New Journal of Chemistry. - : Royal Society of Chemistry (RSC). - 1369-9261 .- 1144-0546. ; 34:10, s. 2118-2121

Related links:: http://dx.doi.org/10...; show more...; https://lup.lub.lu.s...; https://doi.org/10.1...; show less...

Abstract Subject headings

Reaction of the ligand 2-(N-isopropyl-N-{(2-pyridyl)methyl}aminomethyl)- 6-(N-(carboxymethyl)-N-((2-pyridyl)-methyl) aminomethyl)- 4-methylphenol (H2IPCPMP) with two equivalents of Fe(ClO4)(2) and two equivalents of sodium pivalate in air leads to the formation of the mu-oxido, mu-carboxylato-bridged diiron complex [{Fe(H-IPCPMP)}(2)(mu-O)(Piv)]ClO4 (1) (Piv = pivalate). Complex 1 is capable of catalysing the oxidation of cyclohexane or 1,2-cis-dimethylcyclohexane by hydrogen peroxide, leading to the formation of the corresponding cyclohexanone and cyclohexanol, as well as a small amount of cyclohexyl hydroperoxide.

By the author/editor: Jarenmark, Marti ...; Turitsyna, Elena ...; Haukka, Matti; Shteinman, Alber ...; Nordlander, Ebbe

About the subject

NATURAL SCIENCES: NATURAL SCIENCES; and Physical Science ...; and Atom and Molecul ...

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