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Sökning: WFRF:(Zhou Hongwei) > (2020-2024) > Long-wavelength dua...

LIBRIS Formathandbok  (Information om MARC21)
FältnamnIndikatorerMetadata
00004302naa a2200421 4500
001oai:DiVA.org:liu-206622
003SwePub
008240821s2024 | |||||||||||000 ||eng|
024a https://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-2066222 URI
024a https://doi.org/10.1039/d4tc01855a2 DOI
040 a (SwePub)liu
041 a engb eng
042 9 SwePub
072 7a ref2 swepub-contenttype
072 7a art2 swepub-publicationtype
100a Li, Yiranu Fudan Univ, Peoples R China; Donghua Univ, Peoples R China4 aut
2451 0a Long-wavelength dual-state luminescent naphthalimide derivatives for bio-imaging
264 c 2024
264 1b ROYAL SOC CHEMISTRY,c 2024
338 a print2 rdacarrier
500 a Funding Agencies|National Natural Science Foundation of China [22375036]; International Cooperation Fund of Science and Technology Commission of Shanghai Municipality [21130750100]; Natural Science Foundation of Shanghai [21ZR1402000]; Fundamental Research Funds for the Central Universities [2232022A-03]; Swedish Research Council [2020-04600]; European Union [101077649]; Olle Engkvists Stiftelse (Sweden) [212-0136]; Swedish Research Council [2022-06725]
520 a Developing fluorescent materials with long-wavelength emission, a large Stokes shift, dual-state emission, and long emissive lifetime is highly challenging. Herein, we combined the donor-pi-acceptor (D-pi-A) structure, alkyl chain, and J-aggregation to obtain four-in-one long-wavelength emission dyes. By introducing a triphenylamine or N,N-dimethylaminomine moiety into naphthalimide to construct large conjugate D-pi-A structures, long-wavelength luminescence with a large Stokes shift can be obtained in the solution state due to the large conjugate structure and the intramolecular charge transfer effect. The distorted donor structure and long alkyl chains inhibit the face-to-face stacking of molecules to achieve long-wavelength fluorescence in the powder state. Moreover, the naphthalimide group with a planar rigid structure can specifically drive molecules to form J-aggregates in the powder state, prolonging the excited state lifetimes for a longer fluorescence lifetime. The longest emission wavelength was up to 831 nm with the largest Stokes shift of 383 nm in the solution of compound 2. However, the longest fluorescence lifetime of 7.28 ns can be observed in the powder state of compound 1. Hence, these naphthalimide derivatives can effectively be applied to viscosity-responsive fluorescence lifetime imaging. This work provides a new strategy for developing multi-state and long-lifetime emissive long-wavelength luminescent molecules. A series of naphthalimide derivatives with long-wavelength emission, large Stokes shift, dual-state emission, and long emissive lifetime were obtained by constructing D-pi-A structures applying in viscosity-responsive fluorescence lifetime imaging.
650 7a NATURVETENSKAPx Fysikx Atom- och molekylfysik och optik0 (SwePub)103022 hsv//swe
650 7a NATURAL SCIENCESx Physical Sciencesx Atom and Molecular Physics and Optics0 (SwePub)103022 hsv//eng
700a Baryshnikov, Glibu Linköpings universitet,Laboratoriet för organisk elektronik,Tekniska fakulteten4 aut0 (Swepub:liu)gliba58
700a Sahoo, Smruti Ranjanu Linköpings universitet,Laboratoriet för organisk elektronik,Tekniska fakulteten,Uppsala Univ, Sweden4 aut0 (Swepub:liu)smrra65
700a Lu, Zhenniu Donghua Univ, Peoples R China4 aut
700a Zhou, Luluu Fudan Univ, Peoples R China4 aut
700a Liu, Lingyanu Donghua Univ, Peoples R China4 aut
700a Feng, Weiu Fudan Univ, Peoples R China4 aut
700a Zhu, Liangliangu Fudan Univ, Peoples R China4 aut
700a Wei, Pengu Donghua Univ, Peoples R China4 aut
700a Wu, Hongweiu Donghua Univ, Peoples R China4 aut
700a Yi, Taou Fudan Univ, Peoples R China; Donghua Univ, Peoples R China4 aut
710a Fudan Univ, Peoples R China; Donghua Univ, Peoples R Chinab Laboratoriet för organisk elektronik4 org
773t Journal of Materials Chemistry Cd : ROYAL SOC CHEMISTRYx 2050-7526x 2050-7534
8564 8u https://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-206622
8564 8u https://doi.org/10.1039/d4tc01855a

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