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Facile one-pot synt...
Facile one-pot synthesis of hybrid compounds based on decavanadate showing water oxidation activity
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- Buvailo, Halyna (author)
- Department of Chemistry,Taras Shevchenko National University of Kyiv, Volodymyrska, Kyiv, Ukraine
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- Pavliuk, Mariia V. (author)
- Uppsala universitet,Fysikalisk kemi
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- Makhankova, Valeriya (author)
- Department of Chemistry,Taras Shevchenko National University of Kyiv, Volodymyrska, Kyiv, Ukraine
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- Kokozay, Vladimir (author)
- Department of Chemistry,Taras Shevchenko National University of Kyiv, Volodymyrska, Kyiv, Ukraine
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- Bon, Volodymyr (author)
- Chair of Inorganic Chemistry,Technische Universität Dresden, Dresden, Germany
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- Mijangos, Edgar (author)
- Uppsala universitet,Molekylär biomimetik
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- Shylin, Sergii I. (author)
- Uppsala universitet,Molekylär biomimetik
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- Jezierska, Julia (author)
- Faculty of Chemistry, University of Wroclaw, Wroclaw, Poland
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(creator_code:org_t)
- Elsevier BV, 2020
- 2020
- English.
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In: Inorganic Chemistry Communications. - : Elsevier BV. - 1387-7003 .- 1879-0259. ; 119
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- Herein, we report the synthesis of two hybrid compounds based on decavanadate anion, namely, [Cu(dien)(Hdien)]2[V10O28]·2H2O (1) and (H3dien)2[V10O28]·4H2O (2), where dien = diethylenetriamine, obtained under mild conditions. Both compounds were characterized by elemental, TG/DTA, single crystal and powder X-ray diffraction analyses, IR and EPR spectroscopies. The compound 1 was found to be active as homogeneous photochemical oxidation catalyst of water to dioxygen.
Subject headings
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
Keyword
- Artificial photosynthesis
- renewable energy
- catalysis
- water oxidation
- copper
- Chemistry with specialization in Physical Chemistry
- Kemi med inriktning mot fysikalisk kemi
Publication and Content Type
- ref (subject category)
- art (subject category)
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