Transferring the entatic-state principle to copper photochemistry

↓ Direkt till sidans innehåll
↓ Direkt till sidans sekundära innehåll (sidomenyn)

Search: WFRF:(Andreasson S) > (2015-2019) > Transferring the en...

Transferring the entatic-state principle to copper photochemistry

Dicke, B. (author): Universität Hamburg,University of Hamburg,Center for Free-Electron Laser Science (CFEL)

Hoffmann, A. (author): Rheinisch-Westfaelische Technische Hochschule Aachen,RWTH Aachen University

Stanek, J. (author): Rheinisch-Westfaelische Technische Hochschule Aachen,RWTH Aachen University

Rampp, M. S. (author): Ludwig-Maximilians-Universität München,Ludwig Maximilian University of Munich

Grimm-Lebsanft, B. (author): Universität Hamburg,University of Hamburg,Center for Free-Electron Laser Science (CFEL)

Biebl, F. (author): Center for Free-Electron Laser Science (CFEL),Universität Hamburg,University of Hamburg

Rukser, D. (author): Center for Free-Electron Laser Science (CFEL),Universität Hamburg,University of Hamburg

Maerz, B. (author): Ludwig-Maximilians-Universität München,Ludwig Maximilian University of Munich

Goeries, D. (author): Deutsches Elektronen-Synchrotron (DESY)

Naumova, M. (author): Padernborn University, Germany,Universität Hamburg,University of Hamburg

Biednov, M. (author): Universität Hamburg,University of Hamburg,Center for Free-Electron Laser Science (CFEL)

Neuber, G. (author): Center for Free-Electron Laser Science (CFEL),Universität Hamburg,University of Hamburg

Wetzel, A. (author): Universität Hamburg,University of Hamburg,Center for Free-Electron Laser Science (CFEL)

Hofmann, S. M. (author): Ludwig-Maximilians-Universität München,Ludwig Maximilian University of Munich

Roedig, P. (author): Deutsches Elektronen-Synchrotron (DESY)

Meents, A. (author): Deutsches Elektronen-Synchrotron (DESY)

Bielecki, J. (author): European XFEL GmbH,Uppsala universitet,Uppsala University

Andreasson, Jakob, 1975 (author): Uppsala universitet,Uppsala University,Chalmers tekniska högskola,Chalmers University of Technology

Beyerlein, K. R. (author): Center for Free-Electron Laser Science (CFEL)

Chapman, H. N. (author): Deutsches Elektronen-Synchrotron (DESY),Center for Free-Electron Laser Science (CFEL)

Bressler, C. (author): European XFEL GmbH,Danmarks Tekniske Universitet,Technical University of Denmark,Universität Hamburg,University of Hamburg

Zinth, W. (author): Ludwig-Maximilians-Universität München,Ludwig Maximilian University of Munich

Ruebhausen, M. (author): Universität Hamburg,University of Hamburg,Center for Free-Electron Laser Science (CFEL)

Herres-Pawlis, S. (author): Rheinisch-Westfaelische Technische Hochschule Aachen,RWTH Aachen University

show less...

(creator_code:org_t)

2018-01-15
2018
English.
In: Nature Chemistry. - : Springer Science and Business Media LLC. - 1755-4349 .- 1755-4330. ; 10:3, s. 355-362

Related links:: https://bib-pubdb1.d...; show more...; https://research.cha...; https://doi.org/10.1...; https://research.cha...; https://doi.org/10.1...; show less...

Journal article (peer-reviewed)

Abstract Subject headings

The entatic state denotes a distorted coordination geometry of a complex from its typical arrangement that generates an improvement to its function. The entatic-state principle has been observed to apply to copper electron-transfer proteins and it results in a lowering of the reorganization energy of the electron-transfer process. It is thus crucial for a multitude of biochemical processes, but its importance to photoactive complexes is unexplored. Here we study a copper complex-with a specifically designed constraining ligand geometry-that exhibits metal-to-ligand charge-transfer state lifetimes that are very short. The guanidine-quinoline ligand used here acts on the bis(chelated) copper(I) centre, allowing only small structural changes after photoexcitation that result in very fast structural dynamics. The data were collected using a multimethod approach that featured time-resolved ultraviolet-visible, infrared and X-ray absorption and optical emission spectroscopy. Through supporting density functional calculations, we deliver a detailed picture of the structural dynamics in the picosecond-to-nanosecond time range.

Find in a library

Nature Chemistry (Search for host publication in LIBRIS)

To the university's database

Find more in SwePub

About the subject

NATURAL SCIENCES: NATURAL SCIENCES; and Physical Science ...; and Atom and Molecul ...

NATURAL SCIENCES: NATURAL SCIENCES; and Physical Science ...; and Other Physics To ...

NATURAL SCIENCES: NATURAL SCIENCES; and Chemical Science ...; and Theoretical Chem ...

Articles in the publication: Nature Chemistry

By the university: Chalmers University of Technology

Search outside SwePub

Extend your search to:: Google; Google Book Search; Google Scholar

Kungliga biblioteket hanterar dina personuppgifter i enlighet med EU:s dataskyddsförordning (2018), GDPR. Läs mer om hur det funkar här.
Så här hanterar KB dina uppgifter vid användning av denna tjänst.

LIBRIS.kb.se

Transferring the entatic-state principle to copper photochemistry

Subject headings

Publication and Content Type

Find in a library

To the university's database

Find more in SwePub

Search outside SwePub