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Chemical scissor-mediated structural editing of layered transition metal carbides

Ding, Haoming (author)
Chinese Acad Sci, Peoples R China; Univ Chinese Acad Sci, Peoples R China; CNiTECH, Peoples R China
Li, Youbing (author)
Chinese Acad Sci, Peoples R China; CNiTECH, Peoples R China
Li, Mian (author)
Chinese Acad Sci, Peoples R China; CNiTECH, Peoples R China
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Chen, Ke (author)
Chinese Acad Sci, Peoples R China; CNiTECH, Peoples R China
Liang, Kun (author)
Chinese Acad Sci, Peoples R China; CNiTECH, Peoples R China
Chen, Guoxin (author)
Chinese Acad Sci, Peoples R China; CNiTECH, Peoples R China
Lu, Jun (author)
Linköpings universitet,Tunnfilmsfysik,Tekniska fakulteten
Palisaitis, Justinas (author)
Linköpings universitet,Tunnfilmsfysik,Tekniska fakulteten
Persson, Per O A (author)
Linköpings universitet,Tunnfilmsfysik,Tekniska fakulteten
Eklund, Per (author)
Linköpings universitet,Tunnfilmsfysik,Tekniska fakulteten
Hultman, Lars (author)
Linköpings universitet,Tunnfilmsfysik,Tekniska fakulteten
Du, Shiyu (author)
Chinese Acad Sci, Peoples R China; Univ Chinese Acad Sci, Peoples R China; CNiTECH, Peoples R China
Chai, Zhifang (author)
Chinese Acad Sci, Peoples R China; Univ Chinese Acad Sci, Peoples R China; CNiTECH, Peoples R China
Gogotsi, Yury (author)
Drexel Univ, PA 19104 USA
Huang, Qing (author)
Chinese Acad Sci, Peoples R China; CNiTECH, Peoples R China; Adv Energy Sci & Technol Guangdong Lab, Peoples R China
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 (creator_code:org_t)
AMER ASSOC ADVANCEMENT SCIENCE, 2023
2023
English.
In: Science. - : AMER ASSOC ADVANCEMENT SCIENCE. - 0036-8075 .- 1095-9203. ; 379:6637, s. 1130-1135
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • Intercalated layered materials offer distinctive properties and serve as precursors for important two-dimensional (2D) materials. However, intercalation of non-van der Waals structures, which can expand the family of 2D materials, is difficult. We report a structural editing protocol for layered carbides (MAX phases) and their 2D derivatives (MXenes). Gap-opening and species-intercalating stages were respectively mediated by chemical scissors and intercalants, which created a large family of MAX phases with unconventional elements and structures, as well as MXenes with versatile terminals. The removal of terminals in MXenes with metal scissors and then the stitching of 2D carbide nanosheets with atom intercalation leads to the reconstruction of MAX phases and a family of metal-intercalated 2D carbides, both of which may drive advances in fields ranging from energy to printed electronics.

Subject headings

NATURVETENSKAP  -- Fysik -- Den kondenserade materiens fysik (hsv//swe)
NATURAL SCIENCES  -- Physical Sciences -- Condensed Matter Physics (hsv//eng)

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