L773:1615 4150 OR L773:1615 4169
Sökning: L773:1615 4150 OR L773:1615 4169 > Carbocations as Lew...
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| Fältnamn | Indikatorer | Metadata |
|---|---|---|
| 000 | 02341naa a2200397 4500 | |
| 001 | oai:DiVA.org:kth-144522 | |
| 003 | SwePub | |
| 008 | 140424s2015 | |||||||||||000 ||eng| | |
| 024 | 7 | a https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-1445222 URI |
| 024 | 7 | a https://doi.org/10.1002/adsc.2014006092 DOI |
| 040 | a (SwePub)kth | |
| 041 | a engb eng | |
| 042 | 9 SwePub | |
| 072 | 7 | a ref2 swepub-contenttype |
| 072 | 7 | a art2 swepub-publicationtype |
| 100 | 1 | a Bah, Juhou KTH,Organisk kemi4 aut0 (Swepub:kth)u1gpvftb |
| 245 | 1 0 | a Carbocations as Lewis Acid Catalysts :b Reactivity and Scope |
| 264 | c 2014-11-25 | |
| 264 | 1 | b Wiley,c 2015 |
| 338 | a print2 rdacarrier | |
| 500 | a Updated from manuscript to article.QC 20150306 | |
| 520 | a One class of potential Lewis acids that has received negligible attention as a catalyst is the carbocation. Here we show the potential of triarylmethylium ions as highly powerful Lewis acid catalysts for organic reactions. The Lewis acidity of the triarylmethylium ion can be easily tuned by variation of the electronic properties of the aromatic rings and the catalytic activity of the carbocation is shown to correlate directly to the level of stabilization of the empty p(C)-orbital at the cationic carbon. The versatility of triarylmethylium ions as efficient Lewis acid catalysts for organic reactions is demonstrated in Diels-Alder, aza-Diels-Alder, conjugate addition, halogenation, epoxide rearrangement and intramolecular hetro-ene reactions. | |
| 650 | 7 | a NATURVETENSKAPx Kemix Organisk kemi0 (SwePub)104052 hsv//swe |
| 650 | 7 | a NATURAL SCIENCESx Chemical Sciencesx Organic Chemistry0 (SwePub)104052 hsv//eng |
| 653 | a carbocations | |
| 653 | a catalysis | |
| 653 | a Lewis acids | |
| 653 | a organocatalysis | |
| 653 | a trityl group | |
| 700 | 1 | a Naidu, Veluru Rameshu KTH,Organisk kemi4 aut0 (Swepub:kth)u1r3zhpl |
| 700 | 1 | a Teske, Johannesu KTH,Organisk kemi4 aut0 (Swepub:kth)u1ujsa0b |
| 700 | 1 | a Franzén, Johanu KTH,Organisk kemi4 aut0 (Swepub:kth)u1991vf3 |
| 710 | 2 | a KTHb Organisk kemi4 org |
| 773 | 0 | t Advanced Synthesis and Catalysisd : Wileyg 357:1, s. 148-158q 357:1<148-158x 1615-4150x 1615-4169 |
| 856 | 4 8 | u https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-144522 |
| 856 | 4 8 | u https://doi.org/10.1002/adsc.201400609 |
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