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Bromination-induced...
Bromination-induced stability enhancement with a multivalley optical response signature in guanidinium [C(NH2)(3)](+)-based hybrid perovskite solar cells
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- Banerjee, Amitava (författare)
- Uppsala universitet,Materialteori
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- Chakraborty, Sudip (författare)
- Uppsala universitet,Materialteori
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- Ahuja, Rajeev (författare)
- Uppsala universitet,KTH,Tillämpad materialfysik,Uppsala University, Sweden,Materialteori,Royal Inst Technol KTH, Dept Mat & Engn, Appl Mat Phys, S-10044 Stockholm, Sweden.
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(creator_code:org_t)
- 2017
- 2017
- Engelska.
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Ingår i: Journal of Materials Chemistry A. - : ROYAL SOC CHEMISTRY. - 2050-7488 .- 2050-7496. ; 5:35, s. 18561-18568
- Relaterad länk:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- Guanidinium lead iodide (GAPbI(3)) has been synthesized experimentally, but stability remains an issue, which can be modulated by the insertion of bromine (Br) into the system. We have performed a systematic theoretical investigation to see how bromination can tune the stability of GAPbI(3). The optical properties were also determined, and we have found formation enthalpy-based stability in the perovskite systems, which are active in the visible and IR region even after bromine insertion and additionally more active in the IR range with the transition from GAPbI(3) to GAPbBr(3). The spin orbit coupling effect is considered throughout the band structure calculations. The ensemble of the primary and secondary gaps in the half and fully brominated hybrid perovskites leads to the phenomenon of a multipeak response in the optical spectra, which can be subsequently attributed as multivalley optical response behaviour. This multivalley optical behaviour enables the brominated guanidinium-based hybrid perovskites to exhibit broad light harvesting abilities, and this can be perceived as an idea for natural multi-junction solar cells.
Ämnesord
- TEKNIK OCH TEKNOLOGIER -- Maskinteknik -- Energiteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Mechanical Engineering -- Energy Engineering (hsv//eng)
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
- NATURVETENSKAP -- Fysik -- Den kondenserade materiens fysik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Condensed Matter Physics (hsv//eng)
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